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Open access
International Union of Crystallography (IUCr)
Acta Crystallographica Section E Structure Reports Online
,  volume 69 ,  issue 12 ,  pages m631-m632

2,2′-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato (isopropanolato)aluminium dichloromethane hemisolvate

Publication type: Journal Article
Publication date: 2013-11-06
International Union of Crystallography (IUCr)
SJR: —
CiteScore: —
Impact factor: —
ISSN: 16005368
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract

In the title compound, [Al(C16H14N2O2)(C3H7O)]·0.5CH2Cl2, the salen complex is monomeric and the dichlormethane solvent molecule lies on a crystallographic twofold axis. The central Al atom is fivefold coordinated and possesses a square-based pyramidal environment. The Al—OAlk(ipropyl) bond [1.7404 (14) Å] is much shorter than the Al—OAr(salen) bond lengths [1.7974 (15) and 1.8094 (14) Å]. The isopropyloxo group forms an intramolecular C—H...N hydrogen bond. In the crystal, the complex molecules are linked by weak C—H...O interactions.

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Zaitsev K. V. et al. 2,2′-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato (isopropanolato)aluminium dichloromethane hemisolvate // Acta Crystallographica Section E Structure Reports Online. 2013. Vol. 69. No. 12. p. m631-m632.
GOST all authors (up to 50) Copy
Zaitsev K. V., Kuchuk E. A., Karlov S. S., Zaitseva G. S., Churakov A. V. 2,2′-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato (isopropanolato)aluminium dichloromethane hemisolvate // Acta Crystallographica Section E Structure Reports Online. 2013. Vol. 69. No. 12. p. m631-m632.
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RIS Copy
TY - JOUR
DO - 10.1107/S1600536813029644
UR - https://scripts.iucr.org/cgi-bin/paper?S1600536813029644
TI - 2,2′-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato (isopropanolato)aluminium dichloromethane hemisolvate
T2 - Acta Crystallographica Section E Structure Reports Online
AU - Zaitsev, Kirill V.
AU - Kuchuk, Ekaterina A.
AU - Karlov, Sergey S.
AU - Zaitseva, Galina S.
AU - Churakov, Andrei V.
PY - 2013
DA - 2013/11/06
PB - International Union of Crystallography (IUCr)
SP - m631-m632
IS - 12
VL - 69
PMID - 24454153
SN - 1600-5368
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2013_Zaitsev,
author = {Kirill V. Zaitsev and Ekaterina A. Kuchuk and Sergey S. Karlov and Galina S. Zaitseva and Andrei V. Churakov},
title = {2,2′-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato (isopropanolato)aluminium dichloromethane hemisolvate},
journal = {Acta Crystallographica Section E Structure Reports Online},
year = {2013},
volume = {69},
publisher = {International Union of Crystallography (IUCr)},
month = {nov},
url = {https://scripts.iucr.org/cgi-bin/paper?S1600536813029644},
number = {12},
pages = {m631--m632},
doi = {10.1107/S1600536813029644}
}
MLA
Cite this
MLA Copy
Zaitsev, Kirill V., et al. “2,2′-[Ethane-1,2-diylbis(nitrilomethanylylidene)]diphenolato (isopropanolato)aluminium dichloromethane hemisolvate.” Acta Crystallographica Section E Structure Reports Online, vol. 69, no. 12, Nov. 2013, pp. m631-m632. https://scripts.iucr.org/cgi-bin/paper?S1600536813029644.