Open Access
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volume 72
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issue 12
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pages 1718-1723
Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures
Publication type: Journal Article
Publication date: 2016-11-04
scimago Q4
wos Q4
SJR: 0.197
CiteScore: 1.2
Impact factor: 0.6
ISSN: 20569890
PubMed ID:
27980815
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
Poly[tetra-μ2-acetato-κ8O:O′-bis(μ2-benzene-1,2-diamine-κ2N:N′)dicadmium], [Cd2(CH3COO)4(C6H8N2)2]n, (I), and poly[[(μ2-acetato-κ2O:O′)(acetato-κ2O,O′)(μ2-benzene-1,3-diamine-κ2N:N′)cadmium] hemihydrate], {[Cd(CH3COO)2(C6H8N2)]·0.5H2O}n, (II), have two-dimensional polymeric structures in which monomeric units are joined by bridging acetate and benzenediamine ligands. Each of the CdIIions has an O4N2coordination environment. The coordination geometries of the symmetry-independent CdIIions are distorted octahedral and distorted trigonal antiprismatic in (I) and distorted antiprismatic in (II). Both compounds exhibit an intralayer hydrogen-bonding network. In addition, the water of hydration in (II) is involved in interlayer hydrogen bonding.
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Geiger D. A., Parsons D. E., Pagano B. A. Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures // Acta Crystallographica Section E: Crystallographic Communications. 2016. Vol. 72. No. 12. pp. 1718-1723.
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Geiger D. A., Parsons D. E., Pagano B. A. Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures // Acta Crystallographica Section E: Crystallographic Communications. 2016. Vol. 72. No. 12. pp. 1718-1723.
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TY - JOUR
DO - 10.1107/S2056989016017382
UR - https://doi.org/10.1107/S2056989016017382
TI - Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures
T2 - Acta Crystallographica Section E: Crystallographic Communications
AU - Geiger, David A.
AU - Parsons, Dylan E.
AU - Pagano, Bracco A.
PY - 2016
DA - 2016/11/04
PB - International Union of Crystallography (IUCr)
SP - 1718-1723
IS - 12
VL - 72
PMID - 27980815
SN - 2056-9890
ER -
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@article{2016_Geiger,
author = {David A. Geiger and Dylan E. Parsons and Bracco A. Pagano},
title = {Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2016},
volume = {72},
publisher = {International Union of Crystallography (IUCr)},
month = {nov},
url = {https://doi.org/10.1107/S2056989016017382},
number = {12},
pages = {1718--1723},
doi = {10.1107/S2056989016017382}
}
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MLA
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Geiger, David A., et al. “Two cadmium coordination polymers with bridging acetate and phenylenediamine ligands that exhibit two-dimensional layered structures.” Acta Crystallographica Section E: Crystallographic Communications, vol. 72, no. 12, Nov. 2016, pp. 1718-1723. https://doi.org/10.1107/S2056989016017382.
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