Open Access
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volume 73
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issue 6
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pages 856-858
Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate
Publication type: Journal Article
Publication date: 2017-05-16
scimago Q4
wos Q4
SJR: 0.197
CiteScore: 1.2
Impact factor: 0.6
ISSN: 20569890
PubMed ID:
28638644
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The structure of the title salt, (C5H7N2)[Fe(C6H4O2)(C6H5O2)], consists of 3-aminopyridinium cations and 1′-carboxyferrocene-1-carboxylate monoanions. The ferrocenyl moiety of the anion adopts a typical sandwich structure, with Fe—C distances in the range 2.0270 (15)–2.0568 (17) Å. The anion possesses an eclipsed conformation, with the torsion angle φ (Csubst—Cpcent—Cpcent— Csubst) equal to 66.0°. The conformations of other 1′-carboxyferrocene-1-carboxylate monoanions are compared and analyzed on the basis of literature data.
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Medved'ko A. V. et al. Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate // Acta Crystallographica Section E: Crystallographic Communications. 2017. Vol. 73. No. 6. pp. 856-858.
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Medved'ko A. V., Churakov A. V., Yu H., Wang L., Vatsadze S. Z. Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate // Acta Crystallographica Section E: Crystallographic Communications. 2017. Vol. 73. No. 6. pp. 856-858.
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TY - JOUR
DO - 10.1107/S2056989017007058
UR - https://scripts.iucr.org/cgi-bin/paper?S2056989017007058
TI - Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate
T2 - Acta Crystallographica Section E: Crystallographic Communications
AU - Medved'ko, Aleksei V.
AU - Churakov, Andrei V.
AU - Yu, Haojie
AU - Wang, Li
AU - Vatsadze, Sergey Z.
PY - 2017
DA - 2017/05/16
PB - International Union of Crystallography (IUCr)
SP - 856-858
IS - 6
VL - 73
PMID - 28638644
SN - 2056-9890
ER -
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BibTex (up to 50 authors)
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@article{2017_Medved'ko,
author = {Aleksei V. Medved'ko and Andrei V. Churakov and Haojie Yu and Li Wang and Sergey Z. Vatsadze},
title = {Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2017},
volume = {73},
publisher = {International Union of Crystallography (IUCr)},
month = {may},
url = {https://scripts.iucr.org/cgi-bin/paper?S2056989017007058},
number = {6},
pages = {856--858},
doi = {10.1107/S2056989017007058}
}
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Medved'ko, Aleksei V., et al. “Crystal structure of 3-Aminopyridinium 1′-carboxyferrocene-1-carboxylate.” Acta Crystallographica Section E: Crystallographic Communications, vol. 73, no. 6, May. 2017, pp. 856-858. https://scripts.iucr.org/cgi-bin/paper?S2056989017007058.