Open Access
,
volume 74
,
issue 4
,
pages 543-547
Crystal structure and catalytic activity of tetrakis(μ 2 -ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O: O ′)bis(ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O, O ′)dilutetium n -heptane disolvate
Publication type: Journal Article
Publication date: 2018-03-23
scimago Q4
wos Q4
SJR: 0.197
CiteScore: 1.2
Impact factor: 0.6
ISSN: 20569890
PubMed ID:
29765763
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The title complex, [Lu2(C17H28O4P)6]·2C7H16, was formed in the reaction between potassium 2,6-di-tert-butyl-4-methylphenyl ethyl phosphate, [K(2,6- t Bu2-4-MeC6H2-O)(EtO)PO2], and LuCl3(H2O)6 in water, followed by vacuum drying and recrystallization from heptane. Its crystal structure has triclinic (P-1) symmetry at 120 K. The lutetium tris(phosphate) complex has a binuclear [Lu2(μ-OPO)4] core and the organophosphate ligand exhibits κ2 O,O′ terminal and μ2-κ1 O:κ1 O′ bridging coordination modes with the LuIII ion being sixfold coordinated. The complex is of interest as a precatalyst in the acrylonitrile polymerization process and displays good catalytic activity under mild conditions.
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Minyaev M. E. et al. Crystal structure and catalytic activity of tetrakis(μ 2 -ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O: O ′)bis(ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O, O ′)dilutetium n -heptane disolvate // Acta Crystallographica Section E: Crystallographic Communications. 2018. Vol. 74. No. 4. pp. 543-547.
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Minyaev M. E., Tavtorkin A. N., Korchagina S. A., Nifant'ev I. E., Churakov A. V. Crystal structure and catalytic activity of tetrakis(μ 2 -ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O: O ′)bis(ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O, O ′)dilutetium n -heptane disolvate // Acta Crystallographica Section E: Crystallographic Communications. 2018. Vol. 74. No. 4. pp. 543-547.
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TY - JOUR
DO - 10.1107/S2056989018004565
UR - https://scripts.iucr.org/cgi-bin/paper?S2056989018004565
TI - Crystal structure and catalytic activity of tetrakis(μ 2 -ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O: O ′)bis(ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O, O ′)dilutetium n -heptane disolvate
T2 - Acta Crystallographica Section E: Crystallographic Communications
AU - Minyaev, Mikhail E.
AU - Tavtorkin, Alexander N.
AU - Korchagina, Sof'ya A.
AU - Nifant'ev, Ilya E.
AU - Churakov, Andrei V.
PY - 2018
DA - 2018/03/23
PB - International Union of Crystallography (IUCr)
SP - 543-547
IS - 4
VL - 74
PMID - 29765763
SN - 2056-9890
ER -
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@article{2018_Minyaev,
author = {Mikhail E. Minyaev and Alexander N. Tavtorkin and Sof'ya A. Korchagina and Ilya E. Nifant'ev and Andrei V. Churakov},
title = {Crystal structure and catalytic activity of tetrakis(μ 2 -ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O: O ′)bis(ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O, O ′)dilutetium n -heptane disolvate},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2018},
volume = {74},
publisher = {International Union of Crystallography (IUCr)},
month = {mar},
url = {https://scripts.iucr.org/cgi-bin/paper?S2056989018004565},
number = {4},
pages = {543--547},
doi = {10.1107/S2056989018004565}
}
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Minyaev, Mikhail E., et al. “Crystal structure and catalytic activity of tetrakis(μ 2 -ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O: O ′)bis(ethyl 2,6-di- tert -butyl-4-methylphenyl phosphato-κ2 O, O ′)dilutetium n -heptane disolvate.” Acta Crystallographica Section E: Crystallographic Communications, vol. 74, no. 4, Mar. 2018, pp. 543-547. https://scripts.iucr.org/cgi-bin/paper?S2056989018004565.