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volume 74
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issue 7
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pages 970-972
Crystal structure of (2,2′-bipyridine-κ2 N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)
Publication type: Journal Article
Publication date: 2018-06-15
scimago Q4
wos Q4
SJR: 0.197
CiteScore: 1.2
Impact factor: 0.6
ISSN: 20569890
PubMed ID:
30002896
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
In the title compound, [( t BuSiMe2O)2MoO2(2,2′-bipyridine)] or [Mo(C6H15OSi)2O2(C10H8N2)], the MoVI atom has a distorted octahedral environment with the siloxy substituents occupying the trans positions. The complex contains a rare (R 3SiO)2 MO2 (M = Mo, W) structural motif and was formed in a reaction between sodium molybdate and tert-butyldimethylsilyl chloride in the presence of 2,2-bipyridine. In the crystal, neighbouring molecules are linked by C—H...O=Mo hydrogen bonds, forming chains propagating along the a-axis direction.
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Minyaev M. E. et al. Crystal structure of (2,2′-bipyridine-κ2 N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) // Acta Crystallographica Section E: Crystallographic Communications. 2018. Vol. 74. No. 7. pp. 970-972.
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Minyaev M. E., Vinogradov A. A., Vinogradov A. A., Nifant'ev I. E., Churakov A. V. Crystal structure of (2,2′-bipyridine-κ2 N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI) // Acta Crystallographica Section E: Crystallographic Communications. 2018. Vol. 74. No. 7. pp. 970-972.
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TY - JOUR
DO - 10.1107/S2056989018008472
UR - https://scripts.iucr.org/cgi-bin/paper?S2056989018008472
TI - Crystal structure of (2,2′-bipyridine-κ2 N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)
T2 - Acta Crystallographica Section E: Crystallographic Communications
AU - Minyaev, Mikhail E.
AU - Vinogradov, Alexander A
AU - Vinogradov, Alexander A.
AU - Nifant'ev, Ilya E.
AU - Churakov, Andrei V.
PY - 2018
DA - 2018/06/15
PB - International Union of Crystallography (IUCr)
SP - 970-972
IS - 7
VL - 74
PMID - 30002896
SN - 2056-9890
ER -
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@article{2018_Minyaev,
author = {Mikhail E. Minyaev and Alexander A Vinogradov and Alexander A. Vinogradov and Ilya E. Nifant'ev and Andrei V. Churakov},
title = {Crystal structure of (2,2′-bipyridine-κ2 N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI)},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2018},
volume = {74},
publisher = {International Union of Crystallography (IUCr)},
month = {jun},
url = {https://scripts.iucr.org/cgi-bin/paper?S2056989018008472},
number = {7},
pages = {970--972},
doi = {10.1107/S2056989018008472}
}
Cite this
MLA
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Minyaev, Mikhail E., et al. “Crystal structure of (2,2′-bipyridine-κ2 N,N′)-trans-bis(tert-butyldimethylsilyloxy)-cis-dioxidomolybdenum(VI).” Acta Crystallographica Section E: Crystallographic Communications, vol. 74, no. 7, Jun. 2018, pp. 970-972. https://scripts.iucr.org/cgi-bin/paper?S2056989018008472.