Open Access
Acta Crystallographica Section E: Crystallographic Communications, volume 76, issue 8, pages 1331-1335
DL-Piperidinium-2-carboxylate bis(hydrogen peroxide): Unusual hydrogen-bonded peroxide chains
Publication type: Journal Article
Publication date: 2020-07-21
Quartile SCImago
Q3
Quartile WOS
—
Impact factor: 0.6
ISSN: 20569890
PubMed ID:
32844024
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The title compound, C6H11NO2·2H2O2, is the richest (by molar ratio) in hydrogen peroxide among the peroxosolvates of aliphatic α-amino acids. The asymmetric unit contains a zwitterionic pipecolinic acid molecule and two hydrogen peroxide molecules. The two crystallographically independent hydrogen peroxide molecules form a different number of hydrogen bonds: one forms two as donor and two as acceptor ([2,2] mode) and the other forms two as donor and one as acceptor ([2,1] mode). The latter hydrogen peroxide molecule forms infinite hydrogen-bonded hydroperoxo chains running along the c-axis direction, which is unusual for aliphatic α-amino acid peroxosolvates.
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American Chemical Society (ACS)
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1 publication, 12.5%
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- We do not take into account publications that without a DOI.
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Navasardyan M. A. et al. DL-Piperidinium-2-carboxylate bis(hydrogen peroxide): Unusual hydrogen-bonded peroxide chains // Acta Crystallographica Section E: Crystallographic Communications. 2020. Vol. 76. No. 8. pp. 1331-1335.
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Navasardyan M. A., Grishanov D. A., Prikhodchenko P. V., Churakov A. V. DL-Piperidinium-2-carboxylate bis(hydrogen peroxide): Unusual hydrogen-bonded peroxide chains // Acta Crystallographica Section E: Crystallographic Communications. 2020. Vol. 76. No. 8. pp. 1331-1335.
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TY - JOUR
DO - 10.1107/S205698902000972X
UR - https://doi.org/10.1107%2FS205698902000972X
TI - DL-Piperidinium-2-carboxylate bis(hydrogen peroxide): Unusual hydrogen-bonded peroxide chains
T2 - Acta Crystallographica Section E: Crystallographic Communications
AU - Navasardyan, Mger A.
AU - Grishanov, Dmitry A.
AU - Prikhodchenko, Petr V.
AU - Churakov, Andrei V.
PY - 2020
DA - 2020/07/21 00:00:00
PB - International Union of Crystallography (IUCr)
SP - 1331-1335
IS - 8
VL - 76
PMID - 32844024
SN - 2056-9890
ER -
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@article{2020_Navasardyan,
author = {Mger A. Navasardyan and Dmitry A. Grishanov and Petr V. Prikhodchenko and Andrei V. Churakov},
title = {DL-Piperidinium-2-carboxylate bis(hydrogen peroxide): Unusual hydrogen-bonded peroxide chains},
journal = {Acta Crystallographica Section E: Crystallographic Communications},
year = {2020},
volume = {76},
publisher = {International Union of Crystallography (IUCr)},
month = {jul},
url = {https://doi.org/10.1107%2FS205698902000972X},
number = {8},
pages = {1331--1335},
doi = {10.1107/S205698902000972X}
}
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Navasardyan, Mger A., et al. “DL-Piperidinium-2-carboxylate bis(hydrogen peroxide): Unusual hydrogen-bonded peroxide chains.” Acta Crystallographica Section E: Crystallographic Communications, vol. 76, no. 8, Jul. 2020, pp. 1331-1335. https://doi.org/10.1107%2FS205698902000972X.