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1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene
Natalia Shustova
1
,
Oren P. Anderson
1
,
Olga V. Boltalina
1
,
Steven H. Strauss
1
,
Ivan E. Kareev
2, 3
Тип публикации: Journal Article
Дата публикации: 2007-12-06
SJR: —
CiteScore: —
Impact factor: —
ISSN: 16005368
PubMed ID:
21200724
General Chemistry
Condensed Matter Physics
General Materials Science
Краткое описание
The title compound, C(72)F(36), is one of four isomers of C(60)(CF(3))(12) for which crystal structures have been obtained. The fullerene mol-ecule has an idealized I(h) C(60) core with the 12 CF(3) groups arranged in an asymmetric fashion on two ribbons of edge-sharing C(6)(CF(3))(2) hexa-gons, a para-meta-para-para-para-meta-para ribbon and a para-meta-para ribbon, giving an overall pmp(3)mp,pmp structure. There are no cage Csp(3)-Csp(3) bonds. The F atoms of two CF(3) groups are disordered over two positions; the site occupancy factors are 0.85/0.15 and 0.73/0.27. There are intra-molecular F⋯F contacts between pairs of CF(3) groups on the same hexa-gon that range from 2.521 (3) to 2.738 (4) Å.
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Shustova N. et al. 1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene // Acta Crystallographica Section E Structure Reports Online. 2007. Vol. 64. No. 1. p. o159.
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Shustova N., Anderson O. P., Boltalina O. V., Strauss S. H., Kareev I. E. 1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene // Acta Crystallographica Section E Structure Reports Online. 2007. Vol. 64. No. 1. p. o159.
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TY - JOUR
DO - 10.1107/s1600536807063647
UR - https://doi.org/10.1107/s1600536807063647
TI - 1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene
T2 - Acta Crystallographica Section E Structure Reports Online
AU - Shustova, Natalia
AU - Anderson, Oren P.
AU - Boltalina, Olga V.
AU - Strauss, Steven H.
AU - Kareev, Ivan E.
PY - 2007
DA - 2007/12/06
PB - International Union of Crystallography (IUCr)
SP - o159
IS - 1
VL - 64
PMID - 21200724
SN - 1600-5368
ER -
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@article{2007_Shustova,
author = {Natalia Shustova and Oren P. Anderson and Olga V. Boltalina and Steven H. Strauss and Ivan E. Kareev},
title = {1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene},
journal = {Acta Crystallographica Section E Structure Reports Online},
year = {2007},
volume = {64},
publisher = {International Union of Crystallography (IUCr)},
month = {dec},
url = {https://doi.org/10.1107/s1600536807063647},
number = {1},
pages = {o159},
doi = {10.1107/s1600536807063647}
}
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Shustova, Natalia, et al. “1,3,7,10,14,17,21,28,31,42,52,55-Dodecakis(trifluoromethyl)- 1,3,7,10,14,17,21,28,31,42,52,55-dodecahydro(C60–Ih)[5,6]fullerene.” Acta Crystallographica Section E Structure Reports Online, vol. 64, no. 1, Dec. 2007, p. o159. https://doi.org/10.1107/s1600536807063647.
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