Luminescent Lanthanide-Based Sensor for H2O Detection in Aprotic Solvents and D2O
Publication type: Journal Article
Publication date: 2019-09-01
scimago Q1
wos Q1
SJR: 1.039
CiteScore: 8.2
Impact factor: 4.5
ISSN: 1530437X, 15581748, 23799153
Electrical and Electronic Engineering
Instrumentation
Abstract
Applied methods for detecting water impurities in organic solvents, such as Fischer titration, include wayward equipment and toxic reagents. This method is inapplicable for detecting H
2
O in D
2
O, but suitable techniques like NMR-, IR-, and mass-spectrometry are costly. We report a low-cost, novel luminescent sensor material based on terbium-europium 3D MOF compound developed for facile, portable, and disposable monitoring of water quantities. Our sensor is able to determine water traces in D
2
O and aprotic organic solvents. Treating the material to solvent leads to the change in intensities ratio of terbium and europium bands in emission spectra depending of water content and nature of solvent. For D
2
O calibrating plot
$\text{I}_{\mathrm {Eu}}/\text{I}_{\mathrm {Tb}}$
–%H
2
O is linear whereas for dioxane and acetonitrile the dependence becomes linear in the coordinates
$\text{I}_{\mathrm {Eu}}/\text{I}_{\mathrm {Tb}}$
-ln(%H
2
O). The results reveal the potential application of developed sensor for ratiometric quantitation of H
2
O admixtures in D
2
O, organic solvents, transformer oil, etc.
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Citations from 2024:
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GOST
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Gontcharenko V. E. et al. Luminescent Lanthanide-Based Sensor for H2O Detection in Aprotic Solvents and D2O // IEEE Sensors Journal. 2019. Vol. 19. No. 17. pp. 7365-7372.
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Gontcharenko V. E., Lunev A. M., Taydakov I. V., Korshunov V. M., Drozdov A. A., Belousov Y. A. Luminescent Lanthanide-Based Sensor for H2O Detection in Aprotic Solvents and D2O // IEEE Sensors Journal. 2019. Vol. 19. No. 17. pp. 7365-7372.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1109/JSEN.2019.2916498
UR - https://doi.org/10.1109/JSEN.2019.2916498
TI - Luminescent Lanthanide-Based Sensor for H2O Detection in Aprotic Solvents and D2O
T2 - IEEE Sensors Journal
AU - Gontcharenko, Victoria E
AU - Lunev, Alexey M
AU - Taydakov, Ilya V.
AU - Korshunov, Vladislav M
AU - Drozdov, Andrey A
AU - Belousov, Yury A.
PY - 2019
DA - 2019/09/01
PB - Institute of Electrical and Electronics Engineers (IEEE)
SP - 7365-7372
IS - 17
VL - 19
SN - 1530-437X
SN - 1558-1748
SN - 2379-9153
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Gontcharenko,
author = {Victoria E Gontcharenko and Alexey M Lunev and Ilya V. Taydakov and Vladislav M Korshunov and Andrey A Drozdov and Yury A. Belousov},
title = {Luminescent Lanthanide-Based Sensor for H2O Detection in Aprotic Solvents and D2O},
journal = {IEEE Sensors Journal},
year = {2019},
volume = {19},
publisher = {Institute of Electrical and Electronics Engineers (IEEE)},
month = {sep},
url = {https://doi.org/10.1109/JSEN.2019.2916498},
number = {17},
pages = {7365--7372},
doi = {10.1109/JSEN.2019.2916498}
}
Cite this
MLA
Copy
Gontcharenko, Victoria E., et al. “Luminescent Lanthanide-Based Sensor for H2O Detection in Aprotic Solvents and D2O.” IEEE Sensors Journal, vol. 19, no. 17, Sep. 2019, pp. 7365-7372. https://doi.org/10.1109/JSEN.2019.2916498.