International Journal of Applied Glass Science, volume 5, issue 3, pages 226-235
Sulfide Glass‐Ceramic Electrolytes for All‐Solid‐State Lithium and Sodium Batteries
Publication type: Journal Article
Publication date: 2014-07-03
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor: 2.1
ISSN: 20411286, 20411294
General Materials Science
Abstract
Sulfide glass-ceramic electrolytes with Li+ or Na+ ion conduction have been developed in last decade. High-temperature phases of Li7P3S11 and cubic Na3PS4 are precipitated from mother glasses, and the obtained glass-ceramics show higher conductivity than the mother glasses. It is difficult to synthesize those high-temperature phases by conventional solid-state reaction, and glass electrolytes are thus important as a precursor for forming high-temperature phases. The highest conductivities at 25°C of 1.1 × 10−2 S/cm for Li+ ion conductor (Li7P3S11) and 7.4 × 10−4 S/cm for Na+ ion conductor (Na3.06P0.94Si0.06S4) are achieved in sulfide glass-ceramic electrolytes. All-solid-state batteries with sulfide glass-ceramic electrolytes were fabricated by cold press at room temperature. Sulfide electrolytes have favorable mechanical properties to form favorable solid–solid contacts in solid-state batteries by pressing without heat treatment. All-solid-state Li-In/S and Na-Sn/TiS2 cells using sulfide glass-ceramic electrolytes operate as secondary batteries and exhibit good cycle performance at room temperature.
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Citations by publishers
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- We do not take into account publications without a DOI.
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Tatsumisago M., Hayashi A. Sulfide Glass‐Ceramic Electrolytes for All‐Solid‐State Lithium and Sodium Batteries // International Journal of Applied Glass Science. 2014. Vol. 5. No. 3. pp. 226-235.
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Tatsumisago M., Hayashi A. Sulfide Glass‐Ceramic Electrolytes for All‐Solid‐State Lithium and Sodium Batteries // International Journal of Applied Glass Science. 2014. Vol. 5. No. 3. pp. 226-235.
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TY - JOUR
DO - 10.1111/ijag.12084
UR - https://doi.org/10.1111/ijag.12084
TI - Sulfide Glass‐Ceramic Electrolytes for All‐Solid‐State Lithium and Sodium Batteries
T2 - International Journal of Applied Glass Science
AU - Tatsumisago, Masahiro
AU - Hayashi, Akitoshi
PY - 2014
DA - 2014/07/03 00:00:00
PB - Wiley
SP - 226-235
IS - 3
VL - 5
SN - 2041-1286
SN - 2041-1294
ER -
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@article{2014_Tatsumisago,
author = {Masahiro Tatsumisago and Akitoshi Hayashi},
title = {Sulfide Glass‐Ceramic Electrolytes for All‐Solid‐State Lithium and Sodium Batteries},
journal = {International Journal of Applied Glass Science},
year = {2014},
volume = {5},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1111/ijag.12084},
number = {3},
pages = {226--235},
doi = {10.1111/ijag.12084}
}
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Tatsumisago, Masahiro, and Akitoshi Hayashi. “Sulfide Glass‐Ceramic Electrolytes for All‐Solid‐State Lithium and Sodium Batteries.” International Journal of Applied Glass Science, vol. 5, no. 3, Jul. 2014, pp. 226-235. https://doi.org/10.1111/ijag.12084.