Journal of the American Ceramic Society, volume 98, issue 10, pages 3352-3360
Phase Diagram of the Li4GeS4–Li3PS4 Quasi-Binary System Containing the Superionic Conductor Li10GeP2S12
2
Battery AT, Advanced Technology 1; TOYOTA MOTOR EUROPE NV/SA; Hoge Wei 33A B-1930 Zaventem Belgium
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Publication type: Journal Article
Publication date: 2015-07-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 3.9
ISSN: 00027820, 15512916
Materials Chemistry
Ceramics and Composites
Abstract
A phase diagram is constructed for the quasi-binary Li4GeS4–Li3PS4 system containing the lithium superionic conductor Li10GeP2S12 (LGPS), having an LGPS-type structure, and the β-Li3PS4-type phase, having a thio-LISICON structure. The LGPS and thio-LISICON intermediate compounds are found to exhibit solid solution ranges and show incongruent melting at 650°C and 560°C, respectively. The end-member Li4GeS4 has a compositional range of 0 < k < 0.3 in [(1−k) Li4GeS4 + k Li3PS4], while the other end-member γ-Li3PS4 has no solid solution range. The crystal structures appearing in the binary systems are the α-, β-, and γ-type Li3PS4 structures and the LGPS-type structure, and these are formed by PS4 tetrahedra with different arrangements in each structure. The phase and structural relationships between the compounds appearing in the Li4GeS4–Li3PS4 system are thus clarified.
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Hori S. et al. Phase Diagram of the Li4GeS4–Li3PS4 Quasi-Binary System Containing the Superionic Conductor Li10GeP2S12 // Journal of the American Ceramic Society. 2015. Vol. 98. No. 10. pp. 3352-3360.
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Hori S., KATO M., Suzuki K., Hirayama M., Kato Y., Kanno R. Phase Diagram of the Li4GeS4–Li3PS4 Quasi-Binary System Containing the Superionic Conductor Li10GeP2S12 // Journal of the American Ceramic Society. 2015. Vol. 98. No. 10. pp. 3352-3360.
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TY - JOUR
DO - 10.1111/jace.13694
UR - https://doi.org/10.1111/jace.13694
TI - Phase Diagram of the Li4GeS4–Li3PS4 Quasi-Binary System Containing the Superionic Conductor Li10GeP2S12
T2 - Journal of the American Ceramic Society
AU - Hori, Satoshi
AU - KATO, Masahiko
AU - Suzuki, Kota
AU - Hirayama, Masaaki
AU - Kato, Yuki
AU - Kanno, Ryoji
PY - 2015
DA - 2015/07/08 00:00:00
PB - Wiley
SP - 3352-3360
IS - 10
VL - 98
SN - 0002-7820
SN - 1551-2916
ER -
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@article{2015_Hori,
author = {Satoshi Hori and Masahiko KATO and Kota Suzuki and Masaaki Hirayama and Yuki Kato and Ryoji Kanno},
title = {Phase Diagram of the Li4GeS4–Li3PS4 Quasi-Binary System Containing the Superionic Conductor Li10GeP2S12},
journal = {Journal of the American Ceramic Society},
year = {2015},
volume = {98},
publisher = {Wiley},
month = {jul},
url = {https://doi.org/10.1111/jace.13694},
number = {10},
pages = {3352--3360},
doi = {10.1111/jace.13694}
}
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MLA
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Hori, Satoshi, et al. “Phase Diagram of the Li4GeS4–Li3PS4 Quasi-Binary System Containing the Superionic Conductor Li10GeP2S12.” Journal of the American Ceramic Society, vol. 98, no. 10, Jul. 2015, pp. 3352-3360. https://doi.org/10.1111/jace.13694.