Journal of the American Ceramic Society, volume 105, issue 5, pages 3252-3260

Controllable Li 3 PS 4 –Li 4 SnS 4 solid electrolytes with affordable conductor and high conductivity for solid‐state battery

Pingping Dong 1
Qing Jiao 1
Zengcheng Zhang 1
Jiang Miao 2
Changgui Lin 1
XIANGHUA ZHANG 3
Hongli Ma 3
Baochen Ma 1
Shixun Dai 1
Tiefeng Xu 4
2
 
Ningbo Institute of Materials Technology and Engineering Chinese Academy of Sciences Ningbo Zhejiang China
3
 
Laboratory of Glasses and Ceramics Institute of Chemical Science University of Rennes 1 UMR CNRS 6226 Rennes France
4
 
Ningbo Institute of Oceanography Ningbo China
Publication typeJournal Article
Publication date2022-01-08
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor3.9
ISSN00027820, 15512916
Materials Chemistry
Ceramics and Composites
Abstract
High ionic conductivity, low grain boundary impedance, and stable electrochemical property have become the focus for all-solid-state lithium–sulfur batteries (ASSLSB). One of the approaches is to promote the rapid diffusion of lithium ions by regulating the chemical bond interactions within the framework. The structure control of P5+ substitution for Sn4+ on lithium-ion transport was explored for a series of Li3PS4–Li4SnS4 glass–ceramic electrolytes. Results showed that the grain boundary impedance of the glass electrolyte was reduced after heat treatments. The formation of LiSnPS microcrystals, a good superionic conductor, was detected by X-ray diffraction tests. Electrochemical experiments obtained the highest conductivity of 29.5 S cm−1 at 100°C and stable electrochemical window from –0.1 to 5 V at 25°C. In addition, the cell battery was assembled with prepared electrolyte, which is promoted as a candidate solid electrolyte material with improved performance for ASSLSB.

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Dong P. et al. Controllable Li 3 PS 4 –Li 4 SnS 4 solid electrolytes with affordable conductor and high conductivity for solid‐state battery // Journal of the American Ceramic Society. 2022. Vol. 105. No. 5. pp. 3252-3260.
GOST all authors (up to 50) Copy
Dong P., Jiao Q., Zhang Z., Miao J., Lin C., ZHANG X., Ma H., Ma B., Dai S., Xu T. Controllable Li 3 PS 4 –Li 4 SnS 4 solid electrolytes with affordable conductor and high conductivity for solid‐state battery // Journal of the American Ceramic Society. 2022. Vol. 105. No. 5. pp. 3252-3260.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1111/jace.18287
UR - https://doi.org/10.1111/jace.18287
TI - Controllable Li 3 PS 4 –Li 4 SnS 4 solid electrolytes with affordable conductor and high conductivity for solid‐state battery
T2 - Journal of the American Ceramic Society
AU - Zhang, Zengcheng
AU - Miao, Jiang
AU - Lin, Changgui
AU - ZHANG, XIANGHUA
AU - Ma, Hongli
AU - Ma, Baochen
AU - Xu, Tiefeng
AU - Jiao, Qing
AU - Dai, Shixun
AU - Dong, Pingping
PY - 2022
DA - 2022/01/08 00:00:00
PB - Wiley
SP - 3252-3260
IS - 5
VL - 105
SN - 0002-7820
SN - 1551-2916
ER -
BibTex |
Cite this
BibTex Copy
@article{2022_Dong,
author = {Zengcheng Zhang and Jiang Miao and Changgui Lin and XIANGHUA ZHANG and Hongli Ma and Baochen Ma and Tiefeng Xu and Qing Jiao and Shixun Dai and Pingping Dong},
title = {Controllable Li 3 PS 4 –Li 4 SnS 4 solid electrolytes with affordable conductor and high conductivity for solid‐state battery},
journal = {Journal of the American Ceramic Society},
year = {2022},
volume = {105},
publisher = {Wiley},
month = {jan},
url = {https://doi.org/10.1111/jace.18287},
number = {5},
pages = {3252--3260},
doi = {10.1111/jace.18287}
}
MLA
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MLA Copy
Dong, Pingping, et al. “Controllable Li 3 PS 4 –Li 4 SnS 4 solid electrolytes with affordable conductor and high conductivity for solid‐state battery.” Journal of the American Ceramic Society, vol. 105, no. 5, Jan. 2022, pp. 3252-3260. https://doi.org/10.1111/jace.18287.
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