Open Access

Science advances, volume 3, issue 4

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

Kun (kelvin) Fu ^{1, 2}

Yunhui Gong ^{1, 2}

Boyang Liu ¹

Yizhou Zhu ¹

Shaomao Xu ^{1, 2}

Yonggang Yao ¹

Wei Luo ¹

Chengwei Wang ^{1, 2}

Steven D Lacey ¹

Jiaqi Dai ¹

Yanan Chen ¹

Yifei Mo ^{1, 2}

Eric Wachsman ^{1, 2}

Liangbing Hu ^{1, 2}

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Materials Science and Engineering, University of Maryland, College Park, MD 20742, USA. |

University of Maryland Energy Research Center, University of Maryland, College Park, MD 20742, USA. |

Publication type: Journal Article

Publication date: 2017-04-07

American Association for the Advancement of Science (AAAS)

Journal: Science advances

Quartile SCImago

Quartile WOS

Impact factor: 13.6

ISSN: 23752548

DOI: 10.1126/sciadv.1601659

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PubMed ID: 28435874

Multidisciplinary

Abstract

Strategy to change the wettability of the solid-state electrolyte against Li and reduce interface resistance. Solid-state batteries are a promising option toward high energy and power densities due to the use of lithium (Li) metal as an anode. Among all solid electrolyte materials ranging from sulfides to oxides and oxynitrides, cubic garnet–type Li7La3Zr2O12 (LLZO) ceramic electrolytes are superior candidates because of their high ionic conductivity (10−3 to 10−4 S/cm) and good stability against Li metal. However, garnet solid electrolytes generally have poor contact with Li metal, which causes high resistance and uneven current distribution at the interface. To address this challenge, we demonstrate a strategy to engineer the garnet solid electrolyte and the Li metal interface by forming an intermediary Li-metal alloy, which changes the wettability of the garnet surface (lithiophobic to lithiophilic) and reduces the interface resistance by more than an order of magnitude: 950 ohm·cm2 for the pristine garnet/Li and 75 ohm·cm2 for the surface-engineered garnet/Li. Li7La2.75Ca0.25Zr1.75Nb0.25O12 (LLCZN) was selected as the solid-state electrolyte (SSE) in this work because of its low sintering temperature, stabilized cubic garnet phase, and high ionic conductivity. This low area-specific resistance enables a solid-state garnet SSE/Li metal configuration and promotes the development of a hybrid electrolyte system. The hybrid system uses the improved solid-state garnet SSE Li metal anode and a thin liquid electrolyte cathode interfacial layer. This work provides new ways to address the garnet SSE wetting issue against Li and get more stable cell performances based on the hybrid electrolyte system for Li-ion, Li-sulfur, and Li-oxygen batteries toward the next generation of Li metal batteries.

By date By citations

Top-30

Citations by journals

	5 10 15 20 25 30 35 40 45
ACS applied materials & interfaces	ACS applied materials & interfaces, 42, 6.26% ACS applied materials & interfaces 42 publications, 6.26%
Energy Storage Materials	Energy Storage Materials, 35, 5.22% Energy Storage Materials 35 publications, 5.22%
Advanced Energy Materials	Advanced Energy Materials, 31, 4.62% Advanced Energy Materials 31 publications, 4.62%
Journal of Materials Chemistry A	Journal of Materials Chemistry A, 29, 4.32% Journal of Materials Chemistry A 29 publications, 4.32%
ACS Applied Energy Materials	ACS Applied Energy Materials, 28, 4.17% ACS Applied Energy Materials 28 publications, 4.17%
Advanced Materials	Advanced Materials, 25, 3.73% Advanced Materials 25 publications, 3.73%
Advanced Functional Materials	Advanced Functional Materials, 23, 3.43% Advanced Functional Materials 23 publications, 3.43%
ACS Energy Letters	ACS Energy Letters, 18, 2.68% ACS Energy Letters 18 publications, 2.68%
Journal of the Electrochemical Society	Journal of the Electrochemical Society, 16, 2.38% Journal of the Electrochemical Society 16 publications, 2.38%
Journal of Power Sources	Journal of Power Sources, 16, 2.38% Journal of Power Sources 16 publications, 2.38%
Nano Energy	Nano Energy, 14, 2.09% Nano Energy 14 publications, 2.09%
Angewandte Chemie	Angewandte Chemie, 14, 2.09% Angewandte Chemie 14 publications, 2.09%
Angewandte Chemie - International Edition	Angewandte Chemie - International Edition, 14, 2.09% Angewandte Chemie - International Edition 14 publications, 2.09%
Electrochimica Acta	Electrochimica Acta, 13, 1.94% Electrochimica Acta 13 publications, 1.94%
Joule	Joule, 11, 1.64% Joule 11 publications, 1.64%
Small	Small, 10, 1.49% Small 10 publications, 1.49%
Chemical Engineering Journal	Chemical Engineering Journal, 10, 1.49% Chemical Engineering Journal 10 publications, 1.49%
Nano Letters	Nano Letters, 9, 1.34% Nano Letters 9 publications, 1.34%
Ceramics International	Ceramics International, 9, 1.34% Ceramics International 9 publications, 1.34%
Energy and Environmental Science	Energy and Environmental Science, 9, 1.34% Energy and Environmental Science 9 publications, 1.34%
Chemistry of Materials	Chemistry of Materials, 8, 1.19% Chemistry of Materials 8 publications, 1.19%
Advanced Science	Advanced Science, 8, 1.19% Advanced Science 8 publications, 1.19%
Batteries & Supercaps	Batteries & Supercaps, 7, 1.04% Batteries & Supercaps 7 publications, 1.04%
Journal of the American Chemical Society	Journal of the American Chemical Society, 6, 0.89% Journal of the American Chemical Society 6 publications, 0.89%
Electrochemical Energy Reviews	Electrochemical Energy Reviews, 6, 0.89% Electrochemical Energy Reviews 6 publications, 0.89%
Chemical Society Reviews	Chemical Society Reviews, 6, 0.89% Chemical Society Reviews 6 publications, 0.89%
Science advances	Science advances, 6, 0.89% Science advances 6 publications, 0.89%
Chemical Reviews	Chemical Reviews, 5, 0.75% Chemical Reviews 5 publications, 0.75%
Nature Communications	Nature Communications, 5, 0.75% Nature Communications 5 publications, 0.75%
	5 10 15 20 25 30 35 40 45

Citations by publishers

	20 40 60 80 100 120 140 160 180
Wiley	Wiley, 175, 26.08% Wiley 175 publications, 26.08%
Elsevier	Elsevier, 170, 25.34% Elsevier 170 publications, 25.34%
American Chemical Society (ACS)	American Chemical Society (ACS), 137, 20.42% American Chemical Society (ACS) 137 publications, 20.42%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 67, 9.99% Royal Society of Chemistry (RSC) 67 publications, 9.99%
Springer Nature	Springer Nature, 40, 5.96% Springer Nature 40 publications, 5.96%
The Electrochemical Society	The Electrochemical Society, 16, 2.38% The Electrochemical Society 16 publications, 2.38%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 14, 2.09% Multidisciplinary Digital Publishing Institute (MDPI) 14 publications, 2.09%
American Association for the Advancement of Science (AAAS)	American Association for the Advancement of Science (AAAS), 6, 0.89% American Association for the Advancement of Science (AAAS) 6 publications, 0.89%
Frontiers Media S.A.	Frontiers Media S.A., 4, 0.6% Frontiers Media S.A. 4 publications, 0.6%
Nonferrous Metals Society of China	Nonferrous Metals Society of China, 4, 0.6% Nonferrous Metals Society of China 4 publications, 0.6%
Taylor & Francis	Taylor & Francis, 4, 0.6% Taylor & Francis 4 publications, 0.6%
American Institute of Physics (AIP)	American Institute of Physics (AIP), 2, 0.3% American Institute of Physics (AIP) 2 publications, 0.3%
Higher Education Press	Higher Education Press, 2, 0.3% Higher Education Press 2 publications, 0.3%
Proceedings of the National Academy of Sciences (PNAS)	Proceedings of the National Academy of Sciences (PNAS), 2, 0.3% Proceedings of the National Academy of Sciences (PNAS) 2 publications, 0.3%
OAE Publishing Inc.	OAE Publishing Inc., 2, 0.3% OAE Publishing Inc. 2 publications, 0.3%
ASME	ASME, 1, 0.15% ASME 1 publication, 0.15%
Bentham Science	Bentham Science, 1, 0.15% Bentham Science 1 publication, 0.15%
Canadian Science Publishing	Canadian Science Publishing, 1, 0.15% Canadian Science Publishing 1 publication, 0.15%
World Scientific	World Scientific, 1, 0.15% World Scientific 1 publication, 0.15%
Korean Ceramic Society	Korean Ceramic Society, 1, 0.15% Korean Ceramic Society 1 publication, 0.15%
Tsinghua University Press	Tsinghua University Press, 1, 0.15% Tsinghua University Press 1 publication, 0.15%
Wuhan University of Technology	Wuhan University of Technology, 1, 0.15% Wuhan University of Technology 1 publication, 0.15%
Chinese Ceramic Society	Chinese Ceramic Society, 1, 0.15% Chinese Ceramic Society 1 publication, 0.15%
Taiwan Institute of Chemical Engineers	Taiwan Institute of Chemical Engineers, 1, 0.15% Taiwan Institute of Chemical Engineers 1 publication, 0.15%
Korean Society of Industrial Engineering Chemistry	Korean Society of Industrial Engineering Chemistry, 1, 0.15% Korean Society of Industrial Engineering Chemistry 1 publication, 0.15%
Japan Society of Applied Physics	Japan Society of Applied Physics, 1, 0.15% Japan Society of Applied Physics 1 publication, 0.15%
IOP Publishing	IOP Publishing, 1, 0.15% IOP Publishing 1 publication, 0.15%
Social Science Electronic Publishing	Social Science Electronic Publishing, 1, 0.15% Social Science Electronic Publishing 1 publication, 0.15%
Oxford University Press	Oxford University Press, 1, 0.15% Oxford University Press 1 publication, 0.15%
	20 40 60 80 100 120 140 160 180

We do not take into account publications without a DOI.
Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
Statistics recalculated weekly.

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GOST Copy

Fu K. (. et al. Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface // Science advances. 2017. Vol. 3. No. 4.

GOST all authors (up to 50) Copy

Fu K. (., Gong Y., Liu B., Zhu Y., Xu S., Yao Y., Luo W., Wang C., Lacey S. D., Dai J., Chen Y., Mo Y., Wachsman E., Hu L. Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface // Science advances. 2017. Vol. 3. No. 4.

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TY - JOUR

DO - 10.1126/sciadv.1601659

UR - https://doi.org/10.1126/sciadv.1601659

TI - Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface

T2 - Science advances

AU - Fu, Kun (kelvin)

AU - Gong, Yunhui

AU - Liu, Boyang

AU - Zhu, Yizhou

AU - Xu, Shaomao

AU - Yao, Yonggang

AU - Luo, Wei

AU - Wang, Chengwei

AU - Lacey, Steven D

AU - Dai, Jiaqi

AU - Chen, Yanan

AU - Mo, Yifei

AU - Wachsman, Eric

AU - Hu, Liangbing

PY - 2017

DA - 2017/04/07 00:00:00

PB - American Association for the Advancement of Science (AAAS)

IS - 4

VL - 3

PMID - 28435874

SN - 2375-2548

ER -

BibTex

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BibTex Copy

@article{2017_Fu,

author = {Kun (kelvin) Fu and Yunhui Gong and Boyang Liu and Yizhou Zhu and Shaomao Xu and Yonggang Yao and Wei Luo and Chengwei Wang and Steven D Lacey and Jiaqi Dai and Yanan Chen and Yifei Mo and Eric Wachsman and Liangbing Hu},

title = {Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface},

journal = {Science advances},

year = {2017},

volume = {3},

publisher = {American Association for the Advancement of Science (AAAS)},

month = {apr},

url = {https://doi.org/10.1126/sciadv.1601659},

number = {4},

doi = {10.1126/sciadv.1601659}

}

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Publisher

American Association for the Advancement of Science (AAAS)

Journal

Science advances

Quartile SCImago

Quartile WOS

Impact factor

13.6

ISSN

23752548 (Electronic)