Open Access

Science

, volume 379 , issue 6630 , pages 399-403

Highly efficient p-i-n perovskite solar cells that endure temperature variations

Guixiang Li ¹

Zhenhuang Su ²

Laura Canil ¹

Declan Hughes ³

Mahmoud H Aldamasy ¹

Janardan Dagar ¹

Sergei Trofimov ¹

Luyao Wang ¹

Weiwei Zuo ⁴

José J Jerónimo Rendon ⁴

Mahdi Malekshahi Byranvand ^{4, 5}

Chenyue Wang ²

Rui Zhu ⁶

Zuhong Zhang ⁶

Feng Yang ⁶

Giuseppe Nasti ⁷

Boris Naydenov ¹

Wing C Tsoi ³

Zhe Li ⁸

Xingyu Gao ²

Zhao‐Kui Wang ⁹

Jia Yu ⁶

Eva Unger ¹

Michael Saliba ^{4, 5}

Meng Li ^{1, 6, 8}

Antonio Abate ^{1, 7}

Hide authors affiliations Show authors affiliations: 9 affiliations

Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, 14109 Berlin, Germany. |

Shanghai Synchrotron Radiation Facility (SSRF), Shanghai Advanced Research Institute, Chinese Academy of Sciences, 239 Zhangheng Road, Shanghai 201204, China. |

SPECIFIC, Department of Materials Science and Engineering, Faculty of Science and Engineering, Swansea University, Bay Campus, Fabian Way, Swansea SA1 8EN, UK. |

⁴

Institute for Photovoltaics (ipv), University of Stuttgart, Pfaffenwaldring 47, D-70569 Stuttgart, Germany. |

⁵

Helmholtz Young Investigator Group FRONTRUNNER, IEK5-Photovoltaics, Forschungszentrum Jülich, 52425 Jülich, Germany. |

⁶

Key Lab for Special Functional Materials of Ministry of Education, National & Local Joint Engineering Research Center for High-efficiency Display and Lighting Technology, School of Materials Science and Engineering, Collaborative Innovation Center of Nano Functional Materials and Applications, Henan University, Kaifeng 475004, China. |

⁷

Department of Chemical, Materials and Production Engineering, University of Naples Federico II. Naples, pzz.le Vincenzo Tecchio 80, 80125 Naples, Italy. |

⁸

School of Engineering and Materials Science (SEMS), Queen Mary University of London, London E1 4NS, UK. |

⁹

Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China. |

Publication type: Journal Article

Publication date: 2023-01-27

American Association for the Advancement of Science (AAAS)

Science

scimago Q1

wos Q1

SJR: 10.416

CiteScore: 48.4

Impact factor: 45.8

ISSN: 00368075, 10959203

DOI: 10.1126/science.add7331

Copy DOI

PubMed ID: 36701445

Multidisciplinary

Abstract

Daily temperature variations induce phase transitions and lattice strains in halide perovskites, challenging their stability in solar cells. We stabilized the perovskite black phase and improved solar cell performance using the ordered dipolar structure of β-poly(1,1-difluoroethylene) to control perovskite film crystallization and energy alignment. We demonstrated p-i-n perovskite solar cells with a record power conversion efficiency of 24.6% over 18 square millimeters and 23.1% over 1 square centimeter, which retained 96 and 88% of the efficiency after 1000 hours of 1-sun maximum power point tracking at 25° and 75°C, respectively. Devices under rapid thermal cycling between −60° and +80°C showed no sign of fatigue, demonstrating the impact of the ordered dipolar structure on the operational stability of perovskite solar cells.

Found

3 citations

Pandey Rahul

🥼 🤝

255 publications, 7 068 citations, 70 reviews

3 citations

Hossain M.

🥼 🤝

PhD in Engineering

287 publications, 12 332 citations, 628 reviews

h-index: 60

Bangladesh Atomic Energy Commission

1 citation

Zhidkov Ivan

🥼 🤝

PhD in Physics and Mathematics, associate professor

150 publications, 3 035 citations, 125 reviews

h-index: 29

Ural Federal University

M.N. Mikheev Institute of Metal Physics of the Ural Branch of the Russian Academy of Sciences

Research interests

Hybrid perovskites

Luminescence

Perovskite solar panels

Photoelectron spectroscopy

Radiation physics

X-ray photoelectron spectroscopy

X-ray spectroscopy

1 citation

Makarov Sergey

DSc in Physics and Mathematics, professor

412 publications, 7 779 citations, 62 reviews

h-index: 48

ITMO University

Harbin Engineering University

1 citation

Marunchenko Alexandr

11 publications, 101 citations, 4 reviews

h-index: 6

Lund University

ITMO University

1 citation

Livakas Nikolaos

10 publications, 81 citations

h-index: 6

1 citation

Cacialli Franco

290 publications, 14 681 citations, 11 reviews

h-index: 57

Free University of Bozen-Bolzano

University College London

Research interests

Organic semiconductors

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GOST Copy

Li G. et al. Highly efficient p-i-n perovskite solar cells that endure temperature variations // Science. 2023. Vol. 379. No. 6630. pp. 399-403.

GOST all authors (up to 50) Copy

Li G., Su Z., Canil L., Hughes D., Aldamasy M. H., Dagar J., Trofimov S., Wang L., Zuo W., Jerónimo Rendon J. J., Byranvand M. M., Wang C., Zhu R., Zhang Z., Yang F., Nasti G., Naydenov B., Tsoi W. C., Li Z., Gao X., Wang Z., Yu J., Unger E., Saliba M., Li M., Abate A. Highly efficient p-i-n perovskite solar cells that endure temperature variations // Science. 2023. Vol. 379. No. 6630. pp. 399-403.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1126/science.add7331

UR - https://doi.org/10.1126/science.add7331

TI - Highly efficient p-i-n perovskite solar cells that endure temperature variations

T2 - Science

AU - Li, Guixiang

AU - Su, Zhenhuang

AU - Canil, Laura

AU - Hughes, Declan

AU - Aldamasy, Mahmoud H

AU - Dagar, Janardan

AU - Trofimov, Sergei

AU - Wang, Luyao

AU - Zuo, Weiwei

AU - Jerónimo Rendon, José J

AU - Byranvand, Mahdi Malekshahi

AU - Wang, Chenyue

AU - Zhu, Rui

AU - Zhang, Zuhong

AU - Yang, Feng

AU - Nasti, Giuseppe

AU - Naydenov, Boris

AU - Tsoi, Wing C

AU - Li, Zhe

AU - Gao, Xingyu

AU - Wang, Zhao‐Kui

AU - Yu, Jia

AU - Unger, Eva

AU - Saliba, Michael

AU - Li, Meng

AU - Abate, Antonio

PY - 2023

DA - 2023/01/27

PB - American Association for the Advancement of Science (AAAS)

SP - 399-403

IS - 6630

VL - 379

PMID - 36701445

SN - 0036-8075

SN - 1095-9203

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2023_Li,

author = {Guixiang Li and Zhenhuang Su and Laura Canil and Declan Hughes and Mahmoud H Aldamasy and Janardan Dagar and Sergei Trofimov and Luyao Wang and Weiwei Zuo and José J Jerónimo Rendon and Mahdi Malekshahi Byranvand and Chenyue Wang and Rui Zhu and Zuhong Zhang and Feng Yang and Giuseppe Nasti and Boris Naydenov and Wing C Tsoi and Zhe Li and Xingyu Gao and Zhao‐Kui Wang and Jia Yu and Eva Unger and Michael Saliba and Meng Li and Antonio Abate},

title = {Highly efficient p-i-n perovskite solar cells that endure temperature variations},

journal = {Science},

year = {2023},

volume = {379},

publisher = {American Association for the Advancement of Science (AAAS)},

month = {jan},

url = {https://doi.org/10.1126/science.add7331},

number = {6630},

pages = {399--403},

doi = {10.1126/science.add7331}

}

MLA

Cite this

MLA Copy

Li, Guixiang, et al. “Highly efficient p-i-n perovskite solar cells that endure temperature variations.” Science, vol. 379, no. 6630, Jan. 2023, pp. 399-403. https://doi.org/10.1126/science.add7331.

Publisher

American Association for the Advancement of Science (AAAS)

Journal

Science

scimago Q1

wos Q1

SJR

10.416

CiteScore

48.4

Impact factor

45.8

ISSN

00368075 (Print)

10959203 (Electronic)

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