Physics of the Solid State, volume 62, issue 6, pages 937-941
Specifics of Crystallization of Amorphous TiNiCu Alloys with High Concentrations of Copper
Publication type: Journal Article
Publication date: 2020-06-15
Journal:
Physics of the Solid State
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.6
ISSN: 10637834, 10906460, 17267498
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Abstract
Abstract Ribbons of alloys of the quasi-binary TiNi–TiCu system with 25, 30, 35, and 40 at % copper were fabricated by planar flow casting at a cooling rate of 10 6 K/s. The thickness of the ribbons was 30–50 μm, and their width was 10–20 mm. The structure and phase transformations of alloys were studied using electron microscopy, X-ray diffraction, and differential scanning calorimetry. It was found that the alloys with 25 and 30 at % Cu in the initial state have an amorphous-crystalline structure, which undergoes one-stage polymorphic crystallization of the amorphous state with the formation of austenitic phase B 2 under heating in a calorimeter. When cooled to room temperature, phase B 2 undergoes a martensitic transformation to orthorhombic phase B 19. It was demonstrated that the alloys with 35 and 40 at % Cu become amorphous when quenched and undergo two-stage (primary and eutectic) crystallization under heating. The resulting structure is two-phase (tetragonal phase B 11 (TiCu) with a small fraction of phase B 2). An increase in the concentration of copper leads to a reduction in the onset temperature of crystallization.
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Citations by publishers
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Shelyakov A. et al. Specifics of Crystallization of Amorphous TiNiCu Alloys with High Concentrations of Copper // Physics of the Solid State. 2020. Vol. 62. No. 6. pp. 937-941.
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Shelyakov A., Sitnikov N. N., Khabibullina I. A., Sundeev R. V., Sevryukov O. N. Specifics of Crystallization of Amorphous TiNiCu Alloys with High Concentrations of Copper // Physics of the Solid State. 2020. Vol. 62. No. 6. pp. 937-941.
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TY - JOUR
DO - 10.1134/S1063783420060281
UR - https://doi.org/10.1134%2FS1063783420060281
TI - Specifics of Crystallization of Amorphous TiNiCu Alloys with High Concentrations of Copper
T2 - Physics of the Solid State
AU - Khabibullina, I A
AU - Sundeev, R V
AU - Shelyakov, A.V
AU - Sitnikov, N N
AU - Sevryukov, O N
PY - 2020
DA - 2020/06/15 00:00:00
PB - Pleiades Publishing
SP - 937-941
IS - 6
VL - 62
SN - 1063-7834
SN - 1090-6460
SN - 1726-7498
ER -
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@article{2020_Shelyakov,
author = {I A Khabibullina and R V Sundeev and A.V Shelyakov and N N Sitnikov and O N Sevryukov},
title = {Specifics of Crystallization of Amorphous TiNiCu Alloys with High Concentrations of Copper},
journal = {Physics of the Solid State},
year = {2020},
volume = {62},
publisher = {Pleiades Publishing},
month = {jun},
url = {https://doi.org/10.1134%2FS1063783420060281},
number = {6},
pages = {937--941},
doi = {10.1134/S1063783420060281}
}
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Shelyakov, A.V, et al. “Specifics of Crystallization of Amorphous TiNiCu Alloys with High Concentrations of Copper.” Physics of the Solid State, vol. 62, no. 6, Jun. 2020, pp. 937-941. https://doi.org/10.1134%2FS1063783420060281.
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