Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol
1
College of Advanced Materials Engineering, Jiaxing Nanhu University, Zhejiang, People’s Republic of China
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Jiaxing Key Laboratory of Preparation and Application of Advanced Materials for Energy Conservation and Emission Reduction, Zhejiang, People’s Republic of China
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3
Jiangxi Open University, Jiangxi, People’s Republic of China
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4
College of Humanities and Arts, Jiaxing Nanhu University, Zhejiang, People’s Republic of China
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6
Zhejiang Engineering Research Center for Arene Sulfonic Acid, Zhejiang, People’s Republic of China
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Publication type: Journal Article
Publication date: 2023-12-29
scimago Q4
wos Q4
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A novel complex (p-cymene)Ru(S2C2B10H9)(PhCH=CCH2OCH(Ph)C≡CH)·CH2Cl2 based on the ortho-carborane-1,2-dithiolate ligand and 1-phenyl-2-propyn-1-ol has been synthesized successfully and characterized by IR, NMR, MS, elemental analysis and single-crystal X-ray diffraction. The complex crystallizes in monoclinic system, space group P21/n with: a = 10.221(4) Å, b = 14.912(6) Å, c = 24.182(10) Å, α = 90.00°, β = 99.096(6)°, γ = 90.00°, C31H40B10Cl2ORuS2, Mr = 772.82, V = 3639(3) Å3, Dc = 1.410 g/cm3, Z = 4, F(000) = 1576, μ(MoKα) = 0.719 mm–1, R = 0.0600 and wR = 0.1561 for 5463 observed reflections (I > 2σ(I)). Structural analysis shows that there are the coordination of C=C bond, the formation of C–S bod, and metal-induced B–H activation with the formation of Ru–B bond.
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Hu J. R. et al. Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol // Journal of Structural Chemistry. 2023. Vol. 64. No. 12. pp. 2343-2350.
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Hu J. R., ZHAO S. Q., Wang J. H., Sun S. Q., Miao C. Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol // Journal of Structural Chemistry. 2023. Vol. 64. No. 12. pp. 2343-2350.
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TY - JOUR
DO - 10.1134/s0022476623120053
UR - https://doi.org/10.1134/s0022476623120053
TI - Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol
T2 - Journal of Structural Chemistry
AU - Hu, J. R.
AU - ZHAO, S. Q.
AU - Wang, J. H.
AU - Sun, S. Q.
AU - Miao, C.-P.
PY - 2023
DA - 2023/12/29
PB - Pleiades Publishing
SP - 2343-2350
IS - 12
VL - 64
SN - 0022-4766
SN - 1573-8779
ER -
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@article{2023_Hu,
author = {J. R. Hu and S. Q. ZHAO and J. H. Wang and S. Q. Sun and C.-P. Miao},
title = {Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol},
journal = {Journal of Structural Chemistry},
year = {2023},
volume = {64},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/s0022476623120053},
number = {12},
pages = {2343--2350},
doi = {10.1134/s0022476623120053}
}
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Hu, J. R., et al. “Synthesis, Structure, and Mechanism of Half-Sandwich Ruthenium Complex Containing OrthoCarborane-1,2-Dithiolate Ligand and 1-Phenyl-2-Propyn-1-ol.” Journal of Structural Chemistry, vol. 64, no. 12, Dec. 2023, pp. 2343-2350. https://doi.org/10.1134/s0022476623120053.