Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 45, issue 12, pages 883-888
Tris(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dionato)(dimethanol)terbium(III): synthesis, crystal structure, and luminescent properties
Publication type: Journal Article
Publication date: 2019-12-01
scimago Q3
wos Q4
SJR: 0.229
CiteScore: 2.4
Impact factor: 1.1
ISSN: 10703284, 16083318
General Chemistry
General Chemical Engineering
Abstract
The neutral complex [Tb(L3)(MeOH)2] was unexpectedly formed as the major product of the reaction of Tb(NO3)3 ∙ 6H2O with 1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dione (HL) and CsOH in aqueous alcohol in 1 : 4 : 4 molar ratio of the reactants. The composition of the complex was confirmed by elemental analysis and X-ray diffraction stidy (CIF file CCDC no. 1876652); luminescent properties of the complex were investigated.
Found
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