Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, volume 50, issue 10, pages 866-872
Monomerization of Binuclear Complex [Zn2(Piv)4(Phen)2] under the Action of Water
A. S. Samulionis
1
,
A G Medvedev
1
,
T A Tripolskaya
1
,
M. A. Kiskin
1
,
P V Prikhodchenko
1
,
I. L. Eremenko
1
,
Publication type: Journal Article
Publication date: 2024-10-01
scimago Q3
wos Q4
SJR: 0.229
CiteScore: 2.4
Impact factor: 1.1
ISSN: 10703284, 16083318
Abstract
The interaction of the binuclear complex [Zn2(Рiv)4(Рhen)2] with water in toluene or acetonitrile results in its monomerization with the formation of compound [Zn(Рiv)2(H2O)(Рhen)], the crystal structure of which is determined by XRD (CIF file CСDC no. 2374361). The individual character of the formed crystalline phase is confirmed by powder XRD. Nanoparticles of zinc peroxide/hydroxide are proposed to be used as a water source for the obtaining of single crystals of [Zn(Рiv)2(H2O)(Рhen)] suitable for XRD.
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