Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: II. Formation of by-products
Publication type: Journal Article
Publication date: 2010-09-01
scimago Q4
wos Q4
SJR: 0.179
CiteScore: 1.4
Impact factor: 0.8
ISSN: 10703632, 16083350
General Chemistry
Abstract
Kinetic laws of formation and expenditure of by-products in the oxidative ammonolysis of 4-bromo-o-xylene in the temperature range 633–693 K were studied. It was shown that 4-bromophthalimide formation at high concentration of ammonia occurs through hydrolysis of 4-bromophthalonitrile; carbon dioxide forms by oxidation of 4-bromo-o-xylene and decarboxylation of 4-bromophthalimide; 4-bromobenzonitrile originates from 4-bromo-o-tolunitrile and 4-bromophthalimide. At low concentration of ammonia additional formation routes of 4-bromophthalimide and CO2 from 4-bromo-o-xylene are realized.
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Bagirzade G. A. Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: II. Formation of by-products // Russian Journal of General Chemistry. 2010. Vol. 80. No. 9. pp. 1779-1785.
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Bagirzade G. A. Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: II. Formation of by-products // Russian Journal of General Chemistry. 2010. Vol. 80. No. 9. pp. 1779-1785.
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TY - JOUR
DO - 10.1134/s1070363210090100
UR - https://doi.org/10.1134/s1070363210090100
TI - Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: II. Formation of by-products
T2 - Russian Journal of General Chemistry
AU - Bagirzade, G A
PY - 2010
DA - 2010/09/01
PB - Pleiades Publishing
SP - 1779-1785
IS - 9
VL - 80
SN - 1070-3632
SN - 1608-3350
ER -
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BibTex (up to 50 authors)
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@article{2010_Bagirzade,
author = {G A Bagirzade},
title = {Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: II. Formation of by-products},
journal = {Russian Journal of General Chemistry},
year = {2010},
volume = {80},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/s1070363210090100},
number = {9},
pages = {1779--1785},
doi = {10.1134/s1070363210090100}
}
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MLA
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Bagirzade, G. A.. “Kinetics of oxidative ammonolysis of 4-bromo-o-xylene: II. Formation of by-products.” Russian Journal of General Chemistry, vol. 80, no. 9, Sep. 2010, pp. 1779-1785. https://doi.org/10.1134/s1070363210090100.