N-Arylation of 1,2,4- and 1,3,4-Oxadiazolones under Activated Aromatic Nucleophilic Substitution Conditions
Publication type: Journal Article
Publication date: 2023-11-01
scimago Q4
wos Q4
SJR: 0.190
CiteScore: 1.3
Impact factor: 0.9
ISSN: 10704280, 16083393
Organic Chemistry
Abstract
The possibilities of N-arylation of 1,2,4-oxadiazol-5(4H)-ones and 1,3,4-oxadiazol-2(3H)-ones with various electron-deficient chloro- and fluorine-substituted nitroarenes under the conditions of the classical activated nucleophilic substitution reaction were studied. A significant difference was found in the reactivity of 1,2,4- and 1,3,4-oxadiazolones in the N-arylation reactions. Methods for the synthesis of N-nitroaryl derivatives of 1,2,4- and 1,3,4-oxadiazolones, providing the target products of sufficient purity in yields of about 65–96%, were developed.
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Konstantinova A. S. et al. N-Arylation of 1,2,4- and 1,3,4-Oxadiazolones under Activated Aromatic Nucleophilic Substitution Conditions // Russian Journal of Organic Chemistry. 2023. Vol. 59. No. 11. pp. 1874-1883.
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Konstantinova A. S., Shetnev A. A., Volobueva A., Korsakov M. K. N-Arylation of 1,2,4- and 1,3,4-Oxadiazolones under Activated Aromatic Nucleophilic Substitution Conditions // Russian Journal of Organic Chemistry. 2023. Vol. 59. No. 11. pp. 1874-1883.
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TY - JOUR
DO - 10.1134/s1070428023110052
UR - https://link.springer.com/10.1134/S1070428023110052
TI - N-Arylation of 1,2,4- and 1,3,4-Oxadiazolones under Activated Aromatic Nucleophilic Substitution Conditions
T2 - Russian Journal of Organic Chemistry
AU - Konstantinova, A. S.
AU - Shetnev, Anton A
AU - Volobueva, Aleksandrina
AU - Korsakov, M. K.
PY - 2023
DA - 2023/11/01
PB - Pleiades Publishing
SP - 1874-1883
IS - 11
VL - 59
SN - 1070-4280
SN - 1608-3393
ER -
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@article{2023_Konstantinova,
author = {A. S. Konstantinova and Anton A Shetnev and Aleksandrina Volobueva and M. K. Korsakov},
title = {N-Arylation of 1,2,4- and 1,3,4-Oxadiazolones under Activated Aromatic Nucleophilic Substitution Conditions},
journal = {Russian Journal of Organic Chemistry},
year = {2023},
volume = {59},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://link.springer.com/10.1134/S1070428023110052},
number = {11},
pages = {1874--1883},
doi = {10.1134/s1070428023110052}
}
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MLA
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Konstantinova, A. S., et al. “N-Arylation of 1,2,4- and 1,3,4-Oxadiazolones under Activated Aromatic Nucleophilic Substitution Conditions.” Russian Journal of Organic Chemistry, vol. 59, no. 11, Nov. 2023, pp. 1874-1883. https://link.springer.com/10.1134/S1070428023110052.