Crystallography Reports, volume 48, issue 4, pages 613-622
Supramolecular architecture of crown-containing styryl dyes: Part I. Crystal and molecular structures of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide
Kuz'mina L. G.
1
,
Churakov A.V.
1
,
Howard J. A. K.
2
,
Fedorova O.A.
3
,
Gromov S P
3
,
Alfimov M.V.
3
Publication type: Journal Article
Publication date: 2003-07-01
Journal:
Crystallography Reports
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 0.7
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The structure of a single crystal of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide (I) is determined by X-ray diffraction. It is established that the single crystal contains positively charged molecules of benzocrown ether photodye (D), K+ cations, I− anions, and water and acetonitrile solvate molecules in the ratio 1: 0.5: 1.5: 1: 1, respectively. The K+ cation and one of the I− anions occupy special positions along the twofold axis. The K+ cation is coordinated by ten oxygen atoms of the crown ether fragments of two D molecules to form the [D2K]3+ complex. Inside the complex, two aromatic quinoline fragments are involved in a stacking interaction. The crossed mutual arrangement of the ethylene fragments and the considerable distance between them exclude the occurrence of intramolecular photochemical [2 + 2]cycloaddition reactions. In the crystal, the [D2K]3+ cationic complexes form stacks along the b axis. The adjacent complexes in a stack are related through the center of symmetry and, therefore, are arranged in a head-to-tail manner. The double bonds of the neighboring molecular cations D in a stack are strictly parallel to each other and are separated by a distance of 3.754 Å. This geometry is favorable to the intermolecular cycloaddition reaction that should result in the formation of the syn head-to-tail isomer.
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- We do not take into account publications that without a DOI.
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Kuz'mina L. G. et al. Supramolecular architecture of crown-containing styryl dyes: Part I. Crystal and molecular structures of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide // Crystallography Reports. 2003. Vol. 48. No. 4. pp. 613-622.
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Kuz'mina L. G., Churakov A., Howard J. A. K., Fedorova O., Gromov S. P., Alfimov M. Supramolecular architecture of crown-containing styryl dyes: Part I. Crystal and molecular structures of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide // Crystallography Reports. 2003. Vol. 48. No. 4. pp. 613-622.
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TY - JOUR
DO - 10.1134/1.1595189
UR - https://doi.org/10.1134%2F1.1595189
TI - Supramolecular architecture of crown-containing styryl dyes: Part I. Crystal and molecular structures of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide
T2 - Crystallography Reports
AU - Kuz'mina, L. G.
AU - Churakov, A.V.
AU - Howard, J. A. K.
AU - Fedorova, O.A.
AU - Alfimov, M.V.
AU - Gromov, S P
PY - 2003
DA - 2003/07/01 00:00:00
PB - Pleiades Publishing
SP - 613-622
IS - 4
VL - 48
SN - 1063-7745
SN - 1562-689X
ER -
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@article{2003_Kuz'mina,
author = {L. G. Kuz'mina and A.V. Churakov and J. A. K. Howard and O.A. Fedorova and M.V. Alfimov and S P Gromov},
title = {Supramolecular architecture of crown-containing styryl dyes: Part I. Crystal and molecular structures of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide},
journal = {Crystallography Reports},
year = {2003},
volume = {48},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134%2F1.1595189},
number = {4},
pages = {613--622},
doi = {10.1134/1.1595189}
}
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Kuz'mina, L. G., et al. “Supramolecular architecture of crown-containing styryl dyes: Part I. Crystal and molecular structures of the acetonitrile solvate monohydrate of the potassium iodide complex with benzo-15-crown-5 ether dye based on methylquinoline iodide.” Crystallography Reports, vol. 48, no. 4, Jul. 2003, pp. 613-622. https://doi.org/10.1134%2F1.1595189.