Crystallography Reports

, volume 49 , issue 5 , pages 767-771

Structure of the undecahydrodecaborate anion B10H11−. Crystal structures of [Ph3PCH2Naph]B10H11 and [Ph3PEt]2B10H10

I N Polyakova ¹

V N Mustyatsa ¹

K Yu Zhizhin ¹

N. T. Kuznetsov ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Kurnakov institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia |

Publication type: Journal Article

Publication date: 2004-09-28

Pleiades Publishing

Crystallography Reports

scimago Q4

wos Q4

SJR: 0.145

CiteScore: 0.8

Impact factor: 0.5

ISSN: 10637745, 1562689X

DOI: 10.1134/1.1803303

Copy DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

The crystal structures of [Ph 3PCH2 Naph]B10H11(I) and [Ph 3PEt]2B10H10 (II) are studied (110 K and room temperature, R = 0.0673 and 0.0609 for 4176 and 953 observed reflections in I and II, respectively). It is unambiguously determined that protonation of the B10H 10 2− anion proceeds at one of the faces of the apical belt and results mainly in a significant lengthening of the edges of the centered face [Be-Be, 1.948(4) Å; Ba-Be, 1.770(5) Å and 1.787(5) Å].

Found

2 citations

Sivaev Igor

DSc in Chemistry

235 publications, 5 849 citations

h-index: 37

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

National Research University Higher School of Economics

Research interests

Boron Chemistry

Coordination Chemistry

Organometallic Chemistry

Top-30

Journals

	1 2 3 4
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 4, 50% Russian Journal of Inorganic Chemistry 4 publications, 50%
Collection of Czechoslovak Chemical Communications	Collection of Czechoslovak Chemical Communications, 1, 12.5% Collection of Czechoslovak Chemical Communications 1 publication, 12.5%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 12.5% Coordination Chemistry Reviews 1 publication, 12.5%
Polyhedron	Polyhedron, 1, 12.5% Polyhedron 1 publication, 12.5%
Dalton Transactions	Dalton Transactions, 1, 12.5% Dalton Transactions 1 publication, 12.5%
	1 2 3 4

Publishers

	1 2 3 4
Pleiades Publishing	Pleiades Publishing, 4, 50% Pleiades Publishing 4 publications, 50%
Elsevier	Elsevier, 2, 25% Elsevier 2 publications, 25%
Institute of Organic Chemistry & Biochemistry	Institute of Organic Chemistry & Biochemistry, 1, 12.5% Institute of Organic Chemistry & Biochemistry 1 publication, 12.5%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 1, 12.5% Royal Society of Chemistry (RSC) 1 publication, 12.5%
	1 2 3 4

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Polyakova I. N. et al. Structure of the undecahydrodecaborate anion B10H11−. Crystal structures of [Ph3PCH2Naph]B10H11 and [Ph3PEt]2B10H10 // Crystallography Reports. 2004. Vol. 49. No. 5. pp. 767-771.

GOST all authors (up to 50) Copy

Polyakova I. N., Mustyatsa V. N., Zhizhin K. Yu., Kuznetsov N. T. Structure of the undecahydrodecaborate anion B10H11−. Crystal structures of [Ph3PCH2Naph]B10H11 and [Ph3PEt]2B10H10 // Crystallography Reports. 2004. Vol. 49. No. 5. pp. 767-771.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1134/1.1803303

UR - https://doi.org/10.1134/1.1803303

TI - Structure of the undecahydrodecaborate anion B10H11−. Crystal structures of [Ph3PCH2Naph]B10H11 and [Ph3PEt]2B10H10

T2 - Crystallography Reports

AU - Polyakova, I N

AU - Mustyatsa, V N

AU - Zhizhin, K Yu

AU - Kuznetsov, N. T.

PY - 2004

DA - 2004/09/28

PB - Pleiades Publishing

SP - 767-771

IS - 5

VL - 49

SN - 1063-7745

SN - 1562-689X

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2004_Polyakova,

author = {I N Polyakova and V N Mustyatsa and K Yu Zhizhin and N. T. Kuznetsov},

title = {Structure of the undecahydrodecaborate anion B10H11−. Crystal structures of [Ph3PCH2Naph]B10H11 and [Ph3PEt]2B10H10},

journal = {Crystallography Reports},

year = {2004},

volume = {49},

publisher = {Pleiades Publishing},

month = {sep},

url = {https://doi.org/10.1134/1.1803303},

number = {5},

pages = {767--771},

doi = {10.1134/1.1803303}

}

MLA

Cite this

MLA Copy

Polyakova, I. N., et al. “Structure of the undecahydrodecaborate anion B10H11−. Crystal structures of [Ph3PCH2Naph]B10H11 and [Ph3PEt]2B10H10.” Crystallography Reports, vol. 49, no. 5, Sep. 2004, pp. 767-771. https://doi.org/10.1134/1.1803303.