Crystallography Reports, volume 50, issue 2, pages 234-253
Structural investigation of model compounds for an acceptor component of a new type of charge-transfer complexes based on viologen analogues. Characteristic features of the molecular and supramolecular structures
Kuz'mina L. G.
1
,
Churakov A.V.
1
,
Howard J. A. K.
2
,
Vedernikov A.I.
3
,
Lobova N.A.
3
,
Botsmanova A A
3
,
Alfimov M.V.
3
,
Publication type: Journal Article
Publication date: 2005-03-01
Journal:
Crystallography Reports
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor: 0.7
ISSN: 10637745, 1562689X
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The crystal and molecular structures of six perchlorates (viologen analogues) are studied. These compounds serve as models of the acceptor component of new charge-transfer complexes containing bis(18-crown-6)stilbene as the donor. The polycyclic aromatic system of divalent cations is demonstrated to be virtually planar. In all cations, the side chains at the nitrogen atoms are oriented in opposite directions almost perpendicular to the plane of the cyclic system. This orientation of the spacers of these carbocations is indicative of their preorganization for the formation of 1: 2 charge-transfer complexes. Analysis of the crystal packings provides evidence that two positive charges on the conjugated systems of the organic cations and the perchlorate anions play a destructive role in the formation of stacking motifs. An increase in the size of the conjugated system and the involvement of an aromatic solvent molecule as an additional building block in a supramolecular system are favorable for the formation of a stacking supramolecular architecture.
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Citations by publishers
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American Chemical Society (ACS)
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3 publications, 33.33%
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2 publications, 22.22%
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Pleiades Publishing
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1 publication, 11.11%
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Springer Nature
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Springer Nature
1 publication, 11.11%
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Elsevier
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Elsevier
1 publication, 11.11%
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Wiley
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Wiley
1 publication, 11.11%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kuz'mina L. G. et al. Structural investigation of model compounds for an acceptor component of a new type of charge-transfer complexes based on viologen analogues. Characteristic features of the molecular and supramolecular structures // Crystallography Reports. 2005. Vol. 50. No. 2. pp. 234-253.
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Kuz'mina L. G., Churakov A., Howard J. A. K., Vedernikov A., Lobova N., Botsmanova A. A., Alfimov M., Gromov S. P. Structural investigation of model compounds for an acceptor component of a new type of charge-transfer complexes based on viologen analogues. Characteristic features of the molecular and supramolecular structures // Crystallography Reports. 2005. Vol. 50. No. 2. pp. 234-253.
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TY - JOUR
DO - 10.1134/1.1887898
UR - https://doi.org/10.1134%2F1.1887898
TI - Structural investigation of model compounds for an acceptor component of a new type of charge-transfer complexes based on viologen analogues. Characteristic features of the molecular and supramolecular structures
T2 - Crystallography Reports
AU - Kuz'mina, L. G.
AU - Churakov, A.V.
AU - Howard, J. A. K.
AU - Vedernikov, A.I.
AU - Lobova, N.A.
AU - Botsmanova, A A
AU - Alfimov, M.V.
AU - Gromov, S P
PY - 2005
DA - 2005/03/01 00:00:00
PB - Pleiades Publishing
SP - 234-253
IS - 2
VL - 50
SN - 1063-7745
SN - 1562-689X
ER -
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@article{2005_Kuz'mina,
author = {L. G. Kuz'mina and A.V. Churakov and J. A. K. Howard and A.I. Vedernikov and N.A. Lobova and A A Botsmanova and M.V. Alfimov and S P Gromov},
title = {Structural investigation of model compounds for an acceptor component of a new type of charge-transfer complexes based on viologen analogues. Characteristic features of the molecular and supramolecular structures},
journal = {Crystallography Reports},
year = {2005},
volume = {50},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134%2F1.1887898},
number = {2},
pages = {234--253},
doi = {10.1134/1.1887898}
}
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Kuz'mina, L. G., et al. “Structural investigation of model compounds for an acceptor component of a new type of charge-transfer complexes based on viologen analogues. Characteristic features of the molecular and supramolecular structures.” Crystallography Reports, vol. 50, no. 2, Mar. 2005, pp. 234-253. https://doi.org/10.1134%2F1.1887898.