Pleiades Publishing
Doklady Chemistry
,  том 474 ,  издание 1 ,  страницы 101-104

Synthesis, structure, and properties of a new multiredox-active Sn(IV) complex based on 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol

Тип публикации: Journal Article
Дата публикации: 2017-05-01
Pleiades Publishing
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SJR: 0.189
CiteScore: 1.6
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ISSN: 00125008, 16083113
General Chemistry
Краткое описание
A new mixed-ligand tin(IV) complex 2 derived from 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol 1 has been prepared and characterized by different physicochemical methods (IR, 1HNMR, and 119Sn NMR spectroscopies). Electrochemical transformations of complex 2 have been studied by cyclic voltammetry. Catecholate and ferrocenyl groups have been found to take part in the redox transformations. Chemical oxidation of complex 2 with silver triflate in a dichloromethane solution has been studied. Formation of monocationic complex 2 + has been detected by EPR spectroscopy. The catecholate ligand has been found to be the primary redox center subjected to oxidation.
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Baryshnikova S. V. et al. Synthesis, structure, and properties of a new multiredox-active Sn(IV) complex based on 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol // Doklady Chemistry. 2017. Vol. 474. No. 1. pp. 101-104.
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Baryshnikova S. V., Bellan E. V., Poddelskii A. I., Smolyaninov I. V., Berberova N. T., Abakumov G. A. Synthesis, structure, and properties of a new multiredox-active Sn(IV) complex based on 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol // Doklady Chemistry. 2017. Vol. 474. No. 1. pp. 101-104.
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TY - JOUR
DO - 10.1134/S0012500817050019
UR - https://doi.org/10.1134/S0012500817050019
TI - Synthesis, structure, and properties of a new multiredox-active Sn(IV) complex based on 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol
T2 - Doklady Chemistry
AU - Baryshnikova, S V
AU - Bellan, E V
AU - Poddelskii, A I
AU - Smolyaninov, I V
AU - Berberova, N T
AU - Abakumov, G. A.
PY - 2017
DA - 2017/05/01
PB - Pleiades Publishing
SP - 101-104
IS - 1
VL - 474
SN - 0012-5008
SN - 1608-3113
ER -
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@article{2017_Baryshnikova,
author = {S V Baryshnikova and E V Bellan and A I Poddelskii and I V Smolyaninov and N T Berberova and G. A. Abakumov},
title = {Synthesis, structure, and properties of a new multiredox-active Sn(IV) complex based on 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol},
journal = {Doklady Chemistry},
year = {2017},
volume = {474},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134/S0012500817050019},
number = {1},
pages = {101--104},
doi = {10.1134/S0012500817050019}
}
MLA
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MLA Скопировать
Baryshnikova, S. V., et al. “Synthesis, structure, and properties of a new multiredox-active Sn(IV) complex based on 3,6-di-tert-butyl-o-benzoquinone and ferrocenylaldimine phenol.” Doklady Chemistry, vol. 474, no. 1, May. 2017, pp. 101-104. https://doi.org/10.1134/S0012500817050019.
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