Doklady Chemistry, volume 475, issue 2, pages 184-187

Lignin conversion to hydrogen-containing gas under the action of microwave radiation

Publication typeJournal Article
Publication date2017-08-01
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor0.8
ISSN00125008, 16083113
General Chemistry
Abstract
The paper describes the carbon dioxide reforming of lignin in the presence of Ni-, Fe, and Ni/Fe-containing active components formed directly on the surface under microwave irradiation. The deposition of 0.1 wt % iron acetylacetonate on the lignin surface results in a sharp increase in the microwave absorption capacity at a 0.5 kW power and induces lignin conversion to hydrogen-containing gas with a degree of hydrogen recovery reaching 90 %. The maximum lignin conversion (65%) is attained in 10 min under microwave irradiation. It was shown for the first time that deposition of metals (Fe and Ni) on lignin can provide for targeted change of the selectivity of reforming to synthesis gas and the process can thus be classified as a plasma catalytic one. Using the obtained results, it is possible to minimize the amount of catalyst and to propose an efficient route for hydrogen and synthesis gas production from lignin waste.

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GOST Copy
Arapova O. V. et al. Lignin conversion to hydrogen-containing gas under the action of microwave radiation // Doklady Chemistry. 2017. Vol. 475. No. 2. pp. 184-187.
GOST all authors (up to 50) Copy
Arapova O. V., Tsodikov M. V., Chistyakov A. V., Kurdyumov S. S., Gekhman A. E. Lignin conversion to hydrogen-containing gas under the action of microwave radiation // Doklady Chemistry. 2017. Vol. 475. No. 2. pp. 184-187.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0012500817080018
UR - https://doi.org/10.1134%2FS0012500817080018
TI - Lignin conversion to hydrogen-containing gas under the action of microwave radiation
T2 - Doklady Chemistry
AU - Kurdyumov, S S
AU - Gekhman, A E
AU - Arapova, O V
AU - Tsodikov, M V
AU - Chistyakov, A. V.
PY - 2017
DA - 2017/08/01 00:00:00
PB - Pleiades Publishing
SP - 184-187
IS - 2
VL - 475
SN - 0012-5008
SN - 1608-3113
ER -
BibTex |
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BibTex Copy
@article{2017_Arapova,
author = {S S Kurdyumov and A E Gekhman and O V Arapova and M V Tsodikov and A. V. Chistyakov},
title = {Lignin conversion to hydrogen-containing gas under the action of microwave radiation},
journal = {Doklady Chemistry},
year = {2017},
volume = {475},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS0012500817080018},
number = {2},
pages = {184--187},
doi = {10.1134/S0012500817080018}
}
MLA
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MLA Copy
Arapova, O. V., et al. “Lignin conversion to hydrogen-containing gas under the action of microwave radiation.” Doklady Chemistry, vol. 475, no. 2, Aug. 2017, pp. 184-187. https://doi.org/10.1134%2FS0012500817080018.
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