Doklady Chemistry, volume 475, issue 2, pages 173-178

Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides

Publication type: Journal Article
Publication date: 2017-08-01
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ISSN: 00125008, 16083113
General Chemistry
Abstract
Molybdenum dioxide (Mo2) synthesized through thermal decomposition of the [MoO2(i-C3H7NHO)2] complex and containing a nanosized fraction has been studied by MALDI-TOF. The composition of clusters of lower nonstoichiometric molybdenum oxide cations in the gas phase has been determined, and theoretical calculations of the thermodynamic stability and structure of the isomers of the most symmetric structures have been performed. Molecular orbitals of the cationic and neutral clusters Mo5O8 and Mo5O9 have been examined, and the aromaticity of the Mo-Mo bonds in metallacycles has been demonstrated.
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Il`in E. G. et al. Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides // Doklady Chemistry. 2017. Vol. 475. No. 2. pp. 173-178.
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Il`in E. G., Beirakhov A. G., Yarzhemskii V. G., Buryak A., Gekhman A. E. Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides // Doklady Chemistry. 2017. Vol. 475. No. 2. pp. 173-178.
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TY - JOUR
DO - 10.1134/S0012500817080080
UR - https://doi.org/10.1134%2FS0012500817080080
TI - Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides
T2 - Doklady Chemistry
AU - Il`in, E. G.
AU - Beirakhov, A G
AU - Yarzhemskii, V G
AU - Gekhman, A E
AU - Buryak, A.K
PY - 2017
DA - 2017/08/01 00:00:00
PB - Pleiades Publishing
SP - 173-178
IS - 2
VL - 475
SN - 0012-5008
SN - 1608-3113
ER -
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@article{2017_Il`in,
author = {E. G. Il`in and A G Beirakhov and V G Yarzhemskii and A E Gekhman and A.K Buryak},
title = {Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides},
journal = {Doklady Chemistry},
year = {2017},
volume = {475},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134%2FS0012500817080080},
number = {2},
pages = {173--178},
doi = {10.1134/S0012500817080080}
}
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Il`in, E. G., et al. “Symmetric cage structures of isomers of nonstoichiometric lower molybdenum oxides.” Doklady Chemistry, vol. 475, no. 2, Aug. 2017, pp. 173-178. https://doi.org/10.1134%2FS0012500817080080.
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