Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type
A. S. Kubasov
1
,
E Yu Matveev
2
,
E S Turyshev
3
,
I N Polyakova
1
,
A Yu Bykov
1
,
A V Kopytin
1
,
K Yu Zhizhin
1, 2
,
N. T. Kuznetsov
1
Publication type: Journal Article
Publication date: 2018-12-13
scimago Q3
wos Q4
SJR: 0.205
CiteScore: 1.3
Impact factor: 1.0
ISSN: 00125008, 16083113
General Chemistry
Abstract
New methods of creation of cyclic bridging and terminal exopolyhedral sulfur-containing substituents in the closo-decaborate anion have been suggested. It has been shown that the reaction of [B10H9SH]2– with 1,2-dibromoethane leads to crosslinking of two cluster anions to give the [B10H9S(CH2)4SB10H9]2– dimer. An analogous reaction with 1,4-dibromobutane yields a derivative with the cyclic tetrahydrothiophene substituent [B10H9S(CH2)4]–. Its interaction with tetrahydrothiophene in the presence of a small excess of trifluoroacetic acid leads to the formation of the neutral disubstituted derivative [B10H8(S(CH2)4)2].
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Kubasov A. S. et al. Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type // Doklady Chemistry. 2018. Vol. 483. No. 1. pp. 263-265.
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Kubasov A. S., Matveev E. Yu., Turyshev E. S., Polyakova I. N., Bykov A. Yu., Kopytin A. V., Zhizhin K. Yu., Kuznetsov N. T. Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type // Doklady Chemistry. 2018. Vol. 483. No. 1. pp. 263-265.
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TY - JOUR
DO - 10.1134/S001250081811006X
UR - https://doi.org/10.1134/S001250081811006X
TI - Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type
T2 - Doklady Chemistry
AU - Kubasov, A. S.
AU - Matveev, E Yu
AU - Turyshev, E S
AU - Polyakova, I N
AU - Bykov, A Yu
AU - Kopytin, A V
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2018
DA - 2018/12/13
PB - Pleiades Publishing
SP - 263-265
IS - 1
VL - 483
SN - 0012-5008
SN - 1608-3113
ER -
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@article{2018_Kubasov,
author = {A. S. Kubasov and E Yu Matveev and E S Turyshev and I N Polyakova and A Yu Bykov and A V Kopytin and K Yu Zhizhin and N. T. Kuznetsov},
title = {Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type},
journal = {Doklady Chemistry},
year = {2018},
volume = {483},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134/S001250081811006X},
number = {1},
pages = {263--265},
doi = {10.1134/S001250081811006X}
}
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MLA
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Kubasov, A. S., et al. “Methods of Creating closo-Decaborate Anion Derivatives with Bridging and Terminal Exopolyhedral Cyclic Substituents of Sulfonium Type.” Doklady Chemistry, vol. 483, no. 1, Dec. 2018, pp. 263-265. https://doi.org/10.1134/S001250081811006X.