Pleiades Publishing
Doklady Chemistry
,  volume 500 ,  issue 2 ,  pages 205-208

Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents

Publication type: Journal Article
Publication date: 2021-10-01
Pleiades Publishing
scimago Q3
wos Q4
SJR: 0.205
CiteScore: 1.3
Impact factor: 1.0
ISSN: 00125008, 16083113
General Chemistry
Abstract
The reaction of sulfonium closo-decaborate derivatives containing carboxyl groups with sulfuryl chloride SO2Cl2 as a halogenating agent was studied. The reaction gave fully halogenated derivatives of the closo-decaborate anion, (n-Bu4N)[2-B10Cl9SR2] (R = –CH2COOEt, –CH2COOH), which was confirmed by 11B, 1H, and 13C NMR and IR spectral data. The structure of the [2-B10Cl9S(CH2COOEt)2]– anion was established using single crystal X-ray diffraction.
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Golubev A. V. et al. Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents // Doklady Chemistry. 2021. Vol. 500. No. 2. pp. 205-208.
GOST all authors (up to 50) Copy
Golubev A. V., Kubasov A. S., Bykov A. Yu., Zhizhin K. Yu., Kuznetsov N. T. Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents // Doklady Chemistry. 2021. Vol. 500. No. 2. pp. 205-208.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0012500821100025
UR - https://doi.org/10.1134/S0012500821100025
TI - Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents
T2 - Doklady Chemistry
AU - Golubev, A. V.
AU - Kubasov, A. S.
AU - Bykov, A Yu
AU - Zhizhin, K Yu
AU - Kuznetsov, N. T.
PY - 2021
DA - 2021/10/01
PB - Pleiades Publishing
SP - 205-208
IS - 2
VL - 500
SN - 0012-5008
SN - 1608-3113
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Golubev,
author = {A. V. Golubev and A. S. Kubasov and A Yu Bykov and K Yu Zhizhin and N. T. Kuznetsov},
title = {Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents},
journal = {Doklady Chemistry},
year = {2021},
volume = {500},
publisher = {Pleiades Publishing},
month = {oct},
url = {https://doi.org/10.1134/S0012500821100025},
number = {2},
pages = {205--208},
doi = {10.1134/S0012500821100025}
}
MLA
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MLA Copy
Golubev, A. V., et al. “Chlorination of Sulfonium Derivatives of closo-Decaborate Anion with Carboxyl-Containing Substituents.” Doklady Chemistry, vol. 500, no. 2, Oct. 2021, pp. 205-208. https://doi.org/10.1134/S0012500821100025.