Application of SERS and SEF Spectroscopy for Detection of Water-Soluble Fullerene–Chlorin Dyads and Chlorin e6
A Yu Belik
1
,
V. I. Kukushkin
2
,
A Yu Rybkin
1
,
N S Goryachev
1
,
P A Mikhailov
3
,
V S Romanova
4
,
O A Kraevaya
1
,
P A Troshin
1, 5
,
A. I. Kotelnikov
1
Publication type: Journal Article
Publication date: 2018-07-31
scimago Q4
wos Q4
SJR: 0.195
CiteScore: 1.7
Impact factor: 1.5
ISSN: 00125016, 16083121
Physical and Theoretical Chemistry
Abstract
Free fluorescence spectra in solution and surface-enhanced Raman scattering (SERS) and surface enhanced fluorescence (SEF) spectra of chlorin e6 and water-soluble covalent fullerene–chlorin dyads have been studied. It has been demonstrated that chlorin e6 and covalent fullerene–chlorin dyads have similar characteristic SERS spectra. The fullerene–chlorin dyads show a pronounced SEF signal, while native chlorin e6 has no fluorescence on surface, which is consistent with the theory predicting an inverse dependence of the SEF intensity on the free fluorescence quantum yield. The concentration dependence of the SEF intensity is linear for the dyads in the range 0.1–2.0 μmol/L. These effects allow one to determine, with high sensitivity, the content of fullerene–chlorin dyads with a low quantum yield of free fluorescence in solutions, which opens wide opportunities for study of biological properties of fullerene–chlorin dyads and their applications in medicine.
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Belik A. Yu. et al. Application of SERS and SEF Spectroscopy for Detection of Water-Soluble Fullerene–Chlorin Dyads and Chlorin e6 // Doklady Physical Chemistry. 2018. Vol. 481. No. 1. pp. 95-99.
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Belik A. Yu., Kukushkin V. I., Rybkin A. Yu., Goryachev N. S., Mikhailov P. A., Romanova V. S., Kraevaya O. A., Troshin P. A., Kotelnikov A. I. Application of SERS and SEF Spectroscopy for Detection of Water-Soluble Fullerene–Chlorin Dyads and Chlorin e6 // Doklady Physical Chemistry. 2018. Vol. 481. No. 1. pp. 95-99.
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RIS
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TY - JOUR
DO - 10.1134/S0012501618070023
UR - https://doi.org/10.1134/S0012501618070023
TI - Application of SERS and SEF Spectroscopy for Detection of Water-Soluble Fullerene–Chlorin Dyads and Chlorin e6
T2 - Doklady Physical Chemistry
AU - Belik, A Yu
AU - Kukushkin, V. I.
AU - Rybkin, A Yu
AU - Goryachev, N S
AU - Mikhailov, P A
AU - Romanova, V S
AU - Kraevaya, O A
AU - Troshin, P A
AU - Kotelnikov, A. I.
PY - 2018
DA - 2018/07/31
PB - Pleiades Publishing
SP - 95-99
IS - 1
VL - 481
SN - 0012-5016
SN - 1608-3121
ER -
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BibTex (up to 50 authors)
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@article{2018_Belik,
author = {A Yu Belik and V. I. Kukushkin and A Yu Rybkin and N S Goryachev and P A Mikhailov and V S Romanova and O A Kraevaya and P A Troshin and A. I. Kotelnikov},
title = {Application of SERS and SEF Spectroscopy for Detection of Water-Soluble Fullerene–Chlorin Dyads and Chlorin e6},
journal = {Doklady Physical Chemistry},
year = {2018},
volume = {481},
publisher = {Pleiades Publishing},
month = {jul},
url = {https://doi.org/10.1134/S0012501618070023},
number = {1},
pages = {95--99},
doi = {10.1134/S0012501618070023}
}
Cite this
MLA
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Belik, A. Yu., et al. “Application of SERS and SEF Spectroscopy for Detection of Water-Soluble Fullerene–Chlorin Dyads and Chlorin e6.” Doklady Physical Chemistry, vol. 481, no. 1, Jul. 2018, pp. 95-99. https://doi.org/10.1134/S0012501618070023.
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