Doklady Physical Chemistry

, volume 499 , issue 2 , pages 73-76

Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum

V A Rozentsvet ¹

N A Sablina ¹

D M Ulyanova ¹

P M Tolstoy ²

I A Novakov ³

Hide authors affiliations Show authors affiliations: 3 affiliations

Institute of Ecology of Volga River Basin, Russian Academy of Sciences, a Branch of the Samara Federal Research Center, Russian Academy of Sciences, Tolyatti, Russia

Institute of Ecology of Volga River Basin RAS

Samara Federal Research Center of the Russian Academy of Sciences

Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russia |

Volgograd State technical University, Volgograd, Russia |

Publication type: Journal Article

Publication date: 2021-08-01

Pleiades Publishing

Doklady Physical Chemistry

scimago Q4

wos Q4

SJR: 0.195

CiteScore: 1.7

Impact factor: 1.5

ISSN: 00125016, 16083121

DOI: 10.1134/S0012501621080017

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Physical and Theoretical Chemistry

Abstract

A new efficient method for the synthesis of soluble thermoplastic polymers of isoprene with softening points in the range from 73 to 160°C has been developed. The method consists in the cationic polymerization of isoprene in dichloromethane or toluene in the presence of catalytic systems based on triethylaluminum in combination with tert-butyl chloride, tert-butyl bromide, 2-chloro-2-methylbutane, or isopropyl chloride.

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Rozentsvet V. A. et al. Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum // Doklady Physical Chemistry. 2021. Vol. 499. No. 2. pp. 73-76.

GOST all authors (up to 50) Copy

Rozentsvet V. A., Sablina N. A., Ulyanova D. M., Tolstoy P. M., Novakov I. A. Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum // Doklady Physical Chemistry. 2021. Vol. 499. No. 2. pp. 73-76.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/S0012501621080017

UR - https://doi.org/10.1134/S0012501621080017

TI - Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum

T2 - Doklady Physical Chemistry

AU - Rozentsvet, V A

AU - Sablina, N A

AU - Ulyanova, D M

AU - Tolstoy, P M

AU - Novakov, I A

PY - 2021

DA - 2021/08/01

PB - Pleiades Publishing

SP - 73-76

IS - 2

VL - 499

SN - 0012-5016

SN - 1608-3121

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2021_Rozentsvet,

author = {V A Rozentsvet and N A Sablina and D M Ulyanova and P M Tolstoy and I A Novakov},

title = {Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum},

journal = {Doklady Physical Chemistry},

year = {2021},

volume = {499},

publisher = {Pleiades Publishing},

month = {aug},

url = {https://doi.org/10.1134/S0012501621080017},

number = {2},

pages = {73--76},

doi = {10.1134/S0012501621080017}

}

MLA

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MLA Copy

Rozentsvet, V. A., et al. “Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum.” Doklady Physical Chemistry, vol. 499, no. 2, Aug. 2021, pp. 73-76. https://doi.org/10.1134/S0012501621080017.