High Energy Chemistry

, том 45 , издание 2 , страницы 99-103

The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation

A A Zezin

V I Feldman

E A Zezina

S I Belopushkin

E V Tsybina

S S Abramchuk

S.B. Zezin

Тип публикации: Journal Article

Дата публикации: 2011-03-08

Pleiades Publishing

High Energy Chemistry

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БС3

SJR: 0.178

CiteScore: 0.9

Impact factor: 0.6

ISSN: 00181439, 16083148

DOI: 10.1134/S0018143911020147

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Physical and Theoretical Chemistry

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The features of nanoparticle formation by the radiation-chemical reduction of Cu2+ ions in polyacrylic acid-polyethyleneimine complexes have been studied. It has been shown that the swollen film/aqueous alcohol medium interphase exchange of the reducing species and the specifics of X-ray energy transfer play an important role in the formation of metal particles in the subsurface layer of polymer matrixes. An analysis of EPR and X-ray diffraction data shows that an acetaldehyde admixture increases the Cu2+ reduction rate of and enables the growth of nanoparticles.

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Иркутский институт химии им. А.Е. Фаворского СО РАН

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Иркутский институт химии им. А.Е. Фаворского СО РАН

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Zezin A. A. et al. The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation // High Energy Chemistry. 2011. Vol. 45. No. 2. pp. 99-103.

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Zezin A. A., Feldman V. I., Zezina E. A., Belopushkin S. I., Tsybina E. V., Abramchuk S. S., Zezin S. The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation // High Energy Chemistry. 2011. Vol. 45. No. 2. pp. 99-103.

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TY - JOUR

DO - 10.1134/S0018143911020147

UR - http://link.springer.com/10.1134/S0018143911020147

TI - The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation

T2 - High Energy Chemistry

AU - Zezin, A A

AU - Feldman, V I

AU - Zezina, E A

AU - Belopushkin, S I

AU - Tsybina, E V

AU - Abramchuk, S S

AU - Zezin, S.B.

PY - 2011

DA - 2011/03/08

PB - Pleiades Publishing

SP - 99-103

IS - 2

VL - 45

SN - 0018-1439

SN - 1608-3148

ER -

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@article{2011_Zezin,

author = {A A Zezin and V I Feldman and E A Zezina and S I Belopushkin and E V Tsybina and S S Abramchuk and S.B. Zezin},

title = {The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation},

journal = {High Energy Chemistry},

year = {2011},

volume = {45},

publisher = {Pleiades Publishing},

month = {mar},

url = {http://link.springer.com/10.1134/S0018143911020147},

number = {2},

pages = {99--103},

doi = {10.1134/S0018143911020147}

}

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Zezin, A. A., et al. “The formation of metal nanoparticles in polyacrylic acid-polyethyleneimine complex upon reduction of copper(II) ions using X-ray irradiation.” High Energy Chemistry, vol. 45, no. 2, Mar. 2011, pp. 99-103. http://link.springer.com/10.1134/S0018143911020147.