Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile
Тип публикации: Journal Article
Дата публикации: 2016-11-12
scimago Q4
wos Q4
БС3
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Краткое описание
Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone (CH1) and its bis(aza-18-crown-6) derivative (CH2) in acetonitrile at ambient temperature and 77 K have been studied. The absorption, fluorescence, and phosphorescence spectra of CH1 and CH2 are similar. The probability of the formation of the triplet state is higher for CH2 molecules (λT-Tmax = 660 nm, lifetime τT ~ 20 μs). The lifetime of the CH1 molecule in the triplet state is estimated at τT ~ 2–3 μs. Photoisomers of CH1 and CH2 are formed along with the triplet state. According to DFT calculation results, the formation of trans–cis photoisomers of CH1 and CH2 is the most energetically favorable.
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Journal of Photochemistry and Photobiology A: Chemistry
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Zakharova G. V. et al. Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile // High Energy Chemistry. 2016. Vol. 50. No. 6. pp. 442-446.
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Zakharova G. V., Zyuzkevich F. S., Gutrov V. N., Nuriev V. N., Vatsadze S. Z., Plotnikov V. G., Avakyan V. G., Gromov S. P., Chibisov A. Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile // High Energy Chemistry. 2016. Vol. 50. No. 6. pp. 442-446.
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TY - JOUR
DO - 10.1134/S0018143916060205
UR - http://link.springer.com/10.1134/S0018143916060205
TI - Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile
T2 - High Energy Chemistry
AU - Zakharova, G V
AU - Zyuzkevich, F S
AU - Gutrov, V N
AU - Nuriev, V N
AU - Vatsadze, S Zh
AU - Plotnikov, V G
AU - Avakyan, V G
AU - Gromov, S P
AU - Chibisov, A.K.
PY - 2016
DA - 2016/11/12
PB - Pleiades Publishing
SP - 442-446
IS - 6
VL - 50
SN - 0018-1439
SN - 1608-3148
ER -
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@article{2016_Zakharova,
author = {G V Zakharova and F S Zyuzkevich and V N Gutrov and V N Nuriev and S Zh Vatsadze and V G Plotnikov and V G Avakyan and S P Gromov and A.K. Chibisov},
title = {Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile},
journal = {High Energy Chemistry},
year = {2016},
volume = {50},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S0018143916060205},
number = {6},
pages = {442--446},
doi = {10.1134/S0018143916060205}
}
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Zakharova, G. V., et al. “Photoinduced processes in bis(diethylaminobenzylidene)cyclohexanone and its bis(aza-18-crown-6)-containing analogue in acetonitrile.” High Energy Chemistry, vol. 50, no. 6, Nov. 2016, pp. 442-446. http://link.springer.com/10.1134/S0018143916060205.
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