Photonics of 18-crown-6-containing styryl dye and its complexes with metal cations
L S Atabekyan
1
,
N A Aleksandrova
1
,
A.I. Vedernikov
1
,
N.A. Lobova
1
,
S P Gromov
1
,
A.K. Chibisov
1
Publication type: Journal Article
Publication date: 2017-05-22
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
Using absorption, luminescence, 1H NMR, and laser kinetic spectroscopies, the photophysical processes and photochemical reactions of 4-[(E)-2-(2,3,5,6,8,9,11,12,14,15-decahydro-1,4,7,10,13,16-benzohexaoxacyclooctadecin-18-yl)vinyl]-1-ethylpyridinium perchlorate and its complexes with lithium, sodium, potassium, calcium, barium, silver, and lead perchlorates in MeCN have been studied. The styryl dye and its complexes with metal cations are capable of emitting normal (prompt) and delayed fluorescence and enter into the trans–cis photoisomerization reaction. The dye molecules in the triplet state participate in the processes of degradation of electronic excitation energy. Triplet–triplet absorption is observed only in the presence of lead cations with a maximum at 470 nm and the deactivation rate constant of the triplet state k = 2.5 × 104 s–1 in a deoxygenated solution.
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Atabekyan L. S. et al. Photonics of 18-crown-6-containing styryl dye and its complexes with metal cations // High Energy Chemistry. 2017. Vol. 51. No. 3. pp. 189-194.
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Atabekyan L. S., Aleksandrova N. A., Vedernikov A., Lobova N., Gromov S. P., Chibisov A. Photonics of 18-crown-6-containing styryl dye and its complexes with metal cations // High Energy Chemistry. 2017. Vol. 51. No. 3. pp. 189-194.
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TY - JOUR
DO - 10.1134/S0018143917030018
UR - http://link.springer.com/10.1134/S0018143917030018
TI - Photonics of 18-crown-6-containing styryl dye and its complexes with metal cations
T2 - High Energy Chemistry
AU - Atabekyan, L S
AU - Aleksandrova, N A
AU - Vedernikov, A.I.
AU - Lobova, N.A.
AU - Gromov, S P
AU - Chibisov, A.K.
PY - 2017
DA - 2017/05/22
PB - Pleiades Publishing
SP - 189-194
IS - 3
VL - 51
SN - 0018-1439
SN - 1608-3148
ER -
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BibTex (up to 50 authors)
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@article{2017_Atabekyan,
author = {L S Atabekyan and N A Aleksandrova and A.I. Vedernikov and N.A. Lobova and S P Gromov and A.K. Chibisov},
title = {Photonics of 18-crown-6-containing styryl dye and its complexes with metal cations},
journal = {High Energy Chemistry},
year = {2017},
volume = {51},
publisher = {Pleiades Publishing},
month = {may},
url = {http://link.springer.com/10.1134/S0018143917030018},
number = {3},
pages = {189--194},
doi = {10.1134/S0018143917030018}
}
Cite this
MLA
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Atabekyan, L. S., et al. “Photonics of 18-crown-6-containing styryl dye and its complexes with metal cations.” High Energy Chemistry, vol. 51, no. 3, May. 2017, pp. 189-194. http://link.springer.com/10.1134/S0018143917030018.
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