High Energy Chemistry, volume 51, issue 3, pages 175-181

Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes

Publication typeJournal Article
Publication date2017-05-22
Quartile SCImago
Q3
Quartile WOS
Q4
Impact factor0.7
ISSN00181439, 16083148
Physical and Theoretical Chemistry
Abstract
The spectral–luminescent, photophysical, and photochemical properties of dichloro-, dibromo-, and diiodo-derivatives of boron dipyrromethenate (BODIPY) have been studied, as well as the feasibility of generating singlet oxygen (1O2) via its photosensitization by the dihalogenated derivatives of BF2 dipyrromethene in solutions. Quantum yields of singlet oxygen have been determined using 1,3-diphenylisobenzofuran as the 1O2 trap. The lowest fluorescence quantum yields have been shown to correspond to the maximum yields of singlet oxygen. It has been found that the best 1O2 photosensitizer among the three test dihalotetraphenylaza- BODIPY is dibromotetraphenylaza-BODIPY, which in addition possesses the highest photostability. Diiodotetramethyl-BODIPY results in the singlet oxygen yield close to unity, but it has significantly lower photostability. The yield of singlet oxygen is affected by the solvent. Dibromtetraphenylaza-BODIPY and diiodotetramethyl-BODIPY may find use as a medium in photodynamic therapy and photocatalysis of oxidation reactions.

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Kuznetsova R. T. et al. Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes // High Energy Chemistry. 2017. Vol. 51. No. 3. pp. 175-181.
GOST all authors (up to 50) Copy
Kuznetsova R. T., Aksenova I. V., Bashkirtsev D. E., Shulev A. S., Antina E. V., Berezin M. B., Bumagina N. A. Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes // High Energy Chemistry. 2017. Vol. 51. No. 3. pp. 175-181.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0018143917030079
UR - https://doi.org/10.1134%2FS0018143917030079
TI - Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes
T2 - High Energy Chemistry
AU - Kuznetsova, R T
AU - Aksenova, Iu V
AU - Bashkirtsev, D E
AU - Shulev, A S
AU - Antina, E V
AU - Berezin, M B
AU - Bumagina, N A
PY - 2017
DA - 2017/05/22 00:00:00
PB - Pleiades Publishing
SP - 175-181
IS - 3
VL - 51
SN - 0018-1439
SN - 1608-3148
ER -
BibTex |
Cite this
BibTex Copy
@article{2017_Kuznetsova
author = {R T Kuznetsova and Iu V Aksenova and D E Bashkirtsev and A S Shulev and E V Antina and M B Berezin and N A Bumagina},
title = {Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes},
journal = {High Energy Chemistry},
year = {2017},
volume = {51},
publisher = {Pleiades Publishing},
month = {may},
url = {https://doi.org/10.1134%2FS0018143917030079},
number = {3},
pages = {175--181},
doi = {10.1134/S0018143917030079}
}
MLA
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MLA Copy
Kuznetsova, R. T., et al. “Determination of the quantum yield of singlet oxygen sensitized by halogenated boron difluoride dipyrromethenes.” High Energy Chemistry, vol. 51, no. 3, May. 2017, pp. 175-181. https://doi.org/10.1134%2FS0018143917030079.
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