Pleiades Publishing
High Energy Chemistry
,  том 52 ,  издание 6 ,  страницы 475-479

Photoprocesses of Bis(diethylaminobenzylidene)cyclopentanone upon Nanosecond Laser and Continuous Irradiation in Acetonitrile

Тип публикации: Journal Article
Дата публикации: 2018-11-01
Pleiades Publishing
scimago Q4
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БС3
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Краткое описание
Spectral, luminescent, and kinetic properties of 2,5-bis(4-diethylaminobenzylidene)cyclopentanone (ketocyanine, A) in air-saturated and oxygen-free acetonitrile have been studied. The ns-Laser and continuous photoexcitation of A results in a product B undergoing in the oxygen-free solution the intersystem crossing into the triplet state with the lifetime of 1 µs. The photoinduced conversion of A into B occurs within a time shorter than 1 µs and is manifested in a decrease in both the fluorescence intensity of A and absorbance at 457 nm and in the appearance of a new absorption at λ > 535 nm. The product B undergoes photoinduced conversion to the parent A via both the excited singlet and triplet states of B.
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High Energy Chemistry
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Gutrov V. N. et al. Photoprocesses of Bis(diethylaminobenzylidene)cyclopentanone upon Nanosecond Laser and Continuous Irradiation in Acetonitrile // High Energy Chemistry. 2018. Vol. 52. No. 6. pp. 475-479.
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Gutrov V. N., Zakharova G. V., Zyuzkevich F. S., Nuriev V. N., Vatsadze S. Z., Gromov S. P., Chibisov A. Photoprocesses of Bis(diethylaminobenzylidene)cyclopentanone upon Nanosecond Laser and Continuous Irradiation in Acetonitrile // High Energy Chemistry. 2018. Vol. 52. No. 6. pp. 475-479.
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TY - JOUR
DO - 10.1134/S0018143918060061
UR - http://link.springer.com/10.1134/S0018143918060061
TI - Photoprocesses of Bis(diethylaminobenzylidene)cyclopentanone upon Nanosecond Laser and Continuous Irradiation in Acetonitrile
T2 - High Energy Chemistry
AU - Gutrov, V N
AU - Zakharova, G V
AU - Zyuzkevich, F S
AU - Nuriev, V N
AU - Vatsadze, S. Z.
AU - Gromov, S P
AU - Chibisov, A.K.
PY - 2018
DA - 2018/11/01
PB - Pleiades Publishing
SP - 475-479
IS - 6
VL - 52
SN - 0018-1439
SN - 1608-3148
ER -
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@article{2018_Gutrov,
author = {V N Gutrov and G V Zakharova and F S Zyuzkevich and V N Nuriev and S. Z. Vatsadze and S P Gromov and A.K. Chibisov},
title = {Photoprocesses of Bis(diethylaminobenzylidene)cyclopentanone upon Nanosecond Laser and Continuous Irradiation in Acetonitrile},
journal = {High Energy Chemistry},
year = {2018},
volume = {52},
publisher = {Pleiades Publishing},
month = {nov},
url = {http://link.springer.com/10.1134/S0018143918060061},
number = {6},
pages = {475--479},
doi = {10.1134/S0018143918060061}
}
MLA
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Gutrov, V. N., et al. “Photoprocesses of Bis(diethylaminobenzylidene)cyclopentanone upon Nanosecond Laser and Continuous Irradiation in Acetonitrile.” High Energy Chemistry, vol. 52, no. 6, Nov. 2018, pp. 475-479. http://link.springer.com/10.1134/S0018143918060061.