photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates
L S Atabekyan
1
,
V G Avakyan
1, 2
,
A.K. Chibisov
1
,
S P Gromov
1, 3
,
S. Z. Vatsadze
1, 3
,
V N Nuriev
1, 3
,
A V Medvedko
1, 3
1
Publication type: Journal Article
Publication date: 2019-03-01
scimago Q4
wos Q4
SJR: 0.178
CiteScore: 0.9
Impact factor: 0.6
ISSN: 00181439, 16083148
Physical and Theoretical Chemistry
Abstract
Photoprocesses in bis(18-crown-6)-1,4-distyrylbenzene (DSB) and its complexes with potassium, barium, and lead perchlorates have been studied in MeCN solutions by absorption, luminescent, and laser kinetic spectroscopy. The DSB molecules in the triplet state participate in the degradation of electron excitation energy, cis–trans isomerization, and fluorescence. The triplet–triplet absorption spectrum has several maximums in the range of 500–700 nm. The most efficient intersystem crossing to the triplet state is observed for the lead perchlorate complex, which is accompanied by a drop in the fluorescence quantum yield and the absence of trans–cis isomerization.
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Atabekyan L. S. et al. photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates // High Energy Chemistry. 2019. Vol. 53. No. 2. pp. 115-124.
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Atabekyan L. S., Avakyan V. G., Chibisov A., Gromov S. P., Vatsadze S. Z., Nuriev V. N., Medvedko A. V. photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates // High Energy Chemistry. 2019. Vol. 53. No. 2. pp. 115-124.
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TY - JOUR
DO - 10.1134/S0018143919020024
UR - http://link.springer.com/10.1134/S0018143919020024
TI - photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates
T2 - High Energy Chemistry
AU - Atabekyan, L S
AU - Avakyan, V G
AU - Chibisov, A.K.
AU - Gromov, S P
AU - Vatsadze, S. Z.
AU - Nuriev, V N
AU - Medvedko, A V
PY - 2019
DA - 2019/03/01
PB - Pleiades Publishing
SP - 115-124
IS - 2
VL - 53
SN - 0018-1439
SN - 1608-3148
ER -
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BibTex (up to 50 authors)
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@article{2019_Atabekyan,
author = {L S Atabekyan and V G Avakyan and A.K. Chibisov and S P Gromov and S. Z. Vatsadze and V N Nuriev and A V Medvedko},
title = {photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates},
journal = {High Energy Chemistry},
year = {2019},
volume = {53},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S0018143919020024},
number = {2},
pages = {115--124},
doi = {10.1134/S0018143919020024}
}
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MLA
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Atabekyan, L. S., et al. “photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates.” High Energy Chemistry, vol. 53, no. 2, Mar. 2019, pp. 115-124. http://link.springer.com/10.1134/S0018143919020024.