Inorganic Materials

, том 48 , издание 1 , страницы 57-61

Lithium intercalation and deintercalation processes in Li4Ti5O12 and LiFePO4

Тип публикации: Journal Article

Дата публикации: 2011-12-23

Pleiades Publishing

Inorganic Materials

scimago Q4

wos Q4

БС2

SJR: 0.183

CiteScore: 1.3

Impact factor: 0.7

ISSN: 00201685, 16083172

DOI: 10.1134/S0020168512010141

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Materials Chemistry

Metals and Alloys

Inorganic Chemistry

General Chemical Engineering

Краткое описание

We have studied the kinetics of electrochemical lithium intercalation and deintercalation processes at different currents in lithium iron phosphate and lithium titanate based composite materials containing fine carbon particles. The results demonstrate that lithium intercalation and deintercalation processes in the electrode materials are characterized by an overvoltage: 4 and 2 mV, respectively, for a cell with a lithium titanate based electrode and 4 and 24 mV for a lithium iron phosphate based cell. Li4Ti5O12 solubility in Li7Ti5O12 is 1.1% (the limit of the solid solution at Li4.03Ti5O12), and Li7Ti5O12 solubility in Li4Ti5O12 is 2.5% (the limit of the solid solution at Li6.93Ti5O12). The conductivity of the phosphate and titanate solid solutions involved in the lithium intercalation and deintercalation processes has been determined.

Найдено

3 цитирования

Воропаева Дарья

к.х.н.

33 публикации, 538 цитирований, 20 рецензий

Индекс Хирша: 14

Институт общей и неорганической химии им. Н.С. Курнакова РАН

Области научных интересов

Зеленые технологии

Литий-ионные аккумуляторы

Мембраные материалы

Натрий-ионные аккумуляторы

2 цитирования

Капаев Роман

42 публикации, 739 цитирований, 21 рецензия

Индекс Хирша: 17

Сколковский институт науки и технологий

Топ-30

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Safronov D. V. et al. Lithium intercalation and deintercalation processes in Li4Ti5O12 and LiFePO4 // Inorganic Materials. 2011. Vol. 48. No. 1. pp. 57-61.

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Safronov D. V., Novikova S. A., Skundin A. M., Yaroslavtsev A. B. Lithium intercalation and deintercalation processes in Li4Ti5O12 and LiFePO4 // Inorganic Materials. 2011. Vol. 48. No. 1. pp. 57-61.

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TY - JOUR

DO - 10.1134/S0020168512010141

UR - https://doi.org/10.1134/S0020168512010141

TI - Lithium intercalation and deintercalation processes in Li4Ti5O12 and LiFePO4

T2 - Inorganic Materials

AU - Safronov, D V

AU - Novikova, S. A.

AU - Skundin, A M

AU - Yaroslavtsev, A. B.

PY - 2011

DA - 2011/12/23

PB - Pleiades Publishing

SP - 57-61

IS - 1

VL - 48

SN - 0020-1685

SN - 1608-3172

ER -

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@article{2011_Safronov,

author = {D V Safronov and S. A. Novikova and A M Skundin and A. B. Yaroslavtsev},

title = {Lithium intercalation and deintercalation processes in Li4Ti5O12 and LiFePO4},

journal = {Inorganic Materials},

year = {2011},

volume = {48},

publisher = {Pleiades Publishing},

month = {dec},

url = {https://doi.org/10.1134/S0020168512010141},

number = {1},

pages = {57--61},

doi = {10.1134/S0020168512010141}

}

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Safronov, D. V., et al. “Lithium intercalation and deintercalation processes in Li4Ti5O12 and LiFePO4.” Inorganic Materials, vol. 48, no. 1, Dec. 2011, pp. 57-61. https://doi.org/10.1134/S0020168512010141.