Synthesis and conductivity studies of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte
Publication type: Journal Article
Publication date: 2016-03-22
scimago Q4
wos Q4
SJR: 0.183
CiteScore: 1.3
Impact factor: 0.7
ISSN: 00201685, 16083172
Materials Chemistry
Metals and Alloys
Inorganic Chemistry
General Chemical Engineering
Abstract
This paper describes the preparation of a lithium ion conducting solid electrolyte with the composition Li1.5Al0.5Ge1.5(PO4)3 by a new liquid-phase method with the use of the water-soluble salts Al(NO3)3 · 9H2O, LiNO3 · 3H2O, and (NH4)2HPO4 and the germano-oxalic acid H2[Ge(C2O4)3]. The synthesized materials have been characterized by X-ray diffraction, differential scanning calorimetry, thermogravimetry, and impedance spectroscopy. The results demonstrate that sintering of the synthesized amorphous powders at a temperature of 650°C leads to the formation of phase-pure Li1.5Al0.5Ge1.5(PO4)3. The ionic conductivity of the electrolyte measured at frequencies from 10 Hz to 2 MHz using pellets with an 86% relative density was 4.2 × 10–4 S/cm.
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Total citations:
14
Citations from 2024:
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(14%)
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Kunshina G. B., Bocharova I. V., Lokshin E. P. Synthesis and conductivity studies of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte // Inorganic Materials. 2016. Vol. 52. No. 3. pp. 279-284.
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Kunshina G. B., Bocharova I. V., Lokshin E. P. Synthesis and conductivity studies of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte // Inorganic Materials. 2016. Vol. 52. No. 3. pp. 279-284.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S0020168516030080
UR - http://link.springer.com/10.1134/S0020168516030080
TI - Synthesis and conductivity studies of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte
T2 - Inorganic Materials
AU - Kunshina, G B
AU - Bocharova, I V
AU - Lokshin, E P
PY - 2016
DA - 2016/03/22
PB - Pleiades Publishing
SP - 279-284
IS - 3
VL - 52
SN - 0020-1685
SN - 1608-3172
ER -
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BibTex (up to 50 authors)
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@article{2016_Kunshina,
author = {G B Kunshina and I V Bocharova and E P Lokshin},
title = {Synthesis and conductivity studies of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte},
journal = {Inorganic Materials},
year = {2016},
volume = {52},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S0020168516030080},
number = {3},
pages = {279--284},
doi = {10.1134/S0020168516030080}
}
Cite this
MLA
Copy
Kunshina, G. B., et al. “Synthesis and conductivity studies of Li1.5Al0.5Ge1.5(PO4)3 solid electrolyte.” Inorganic Materials, vol. 52, no. 3, Mar. 2016, pp. 279-284. http://link.springer.com/10.1134/S0020168516030080.