JETP Letters, volume 90, issue 9, pages 617-622
High-spin-low-spin transition in magnesiowüstite (Mg0.75,Fe0.25)O at high pressures under hydrostatic conditions
Publication type: Journal Article
Publication date: 2010-01-11
Journal:
JETP Letters
Quartile SCImago
Q2
Quartile WOS
Q4
Impact factor: 1.3
ISSN: 00213640, 10906487
Physics and Astronomy (miscellaneous)
Abstract
The spin states of Fe2+ ions in (Mg0.75,Fe0.25)O magnesiowüstite crystals at hydrostatic pressures up to 90 GPa created in a diamond-anvil cell with helium as a pressure-transmitting medium have been investi-gated by transmission and synchrotron Mössbauer spectroscopy at room temperature. An electron transition from the high-spin (HS) state to the low-spin (LS) state (HS-LS crossover) has been observed in the pressure range of 55–70 GPa. The true HS-LS transition occurs in a narrow pressure range and the extension of the electron transition to ∼15 GPa is attributed to the effect of the nearest environment and to thermal fluctuations between the high-spin and low-spin states at finite temperatures. It has been found that the lowest pressure at which the electron HS-LS transition can occur in the Mg1 − xFex system is 50–55 GPa.
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Elsevier
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American Physical Society (APS)
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1 publication, 5%
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Proceedings of the National Academy of Sciences (PNAS)
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1 publication, 5%
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1 publication, 5%
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Lyubutin I. S. et al. High-spin-low-spin transition in magnesiowüstite (Mg0.75,Fe0.25)O at high pressures under hydrostatic conditions // JETP Letters. 2010. Vol. 90. No. 9. pp. 617-622.
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Lyubutin I. S., Gavriliuk A. G., Frolov K., Lin J., Troyan I. A. High-spin-low-spin transition in magnesiowüstite (Mg0.75,Fe0.25)O at high pressures under hydrostatic conditions // JETP Letters. 2010. Vol. 90. No. 9. pp. 617-622.
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TY - JOUR
DO - 10.1134/S0021364009210061
UR - https://doi.org/10.1134%2FS0021364009210061
TI - High-spin-low-spin transition in magnesiowüstite (Mg0.75,Fe0.25)O at high pressures under hydrostatic conditions
T2 - JETP Letters
AU - Lyubutin, I S
AU - Gavriliuk, A. G.
AU - Frolov, K.V.
AU - Lin, J.-F.
AU - Troyan, I A
PY - 2010
DA - 2010/01/11 00:00:00
PB - Pleiades Publishing
SP - 617-622
IS - 9
VL - 90
SN - 0021-3640
SN - 1090-6487
ER -
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@article{2010_Lyubutin,
author = {I S Lyubutin and A. G. Gavriliuk and K.V. Frolov and J.-F. Lin and I A Troyan},
title = {High-spin-low-spin transition in magnesiowüstite (Mg0.75,Fe0.25)O at high pressures under hydrostatic conditions},
journal = {JETP Letters},
year = {2010},
volume = {90},
publisher = {Pleiades Publishing},
month = {jan},
url = {https://doi.org/10.1134%2FS0021364009210061},
number = {9},
pages = {617--622},
doi = {10.1134/S0021364009210061}
}
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Lyubutin, I. S., et al. “High-spin-low-spin transition in magnesiowüstite (Mg0.75,Fe0.25)O at high pressures under hydrostatic conditions.” JETP Letters, vol. 90, no. 9, Jan. 2010, pp. 617-622. https://doi.org/10.1134%2FS0021364009210061.