Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er)
Тип публикации: Journal Article
Дата публикации: 2011-08-01
scimago Q4
wos Q4
БС3
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Rare-earth chromium borates RCr3(BO3)4, where R = La-Er, obtained as a result of spontaneous solutionmelt crystallization and belonging to two polytypic modifications (R32 (D37) and C2/c (C2h6) space groups) are studied by infrared spectroscopy with the factor group analysis of vibrations. Borates with R = La-Nd are shown to crystallize in the monoclinic C2/c space group. Borates with R = Sm-Er in the 1:1 ratio of batch and solvent form rhombohedral (R32 space group) and monoclinic (C2/c space group) phases at the 2.3:1 ratio, except EuCr3(BO3)4 and GdCr3(BO3)4 that have the rhombohedral structure under all crystallization conditions. Both rhombohedral and monoclinic polytypes may contain oppositely ordered layers. Y-, Tm-, Yb-, Lu-chromium borates are not formed.
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Kurazhkovskaya V. S. et al. Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er) // Journal of Structural Chemistry. 2011. Vol. 52. No. 4. pp. 699-707.
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Kurazhkovskaya V. S., Dobretsova E. A., Borovikova E., Mal’tsev V. V., Leonyuk N. I. Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er) // Journal of Structural Chemistry. 2011. Vol. 52. No. 4. pp. 699-707.
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TY - JOUR
DO - 10.1134/S0022476611040081
UR - https://doi.org/10.1134/S0022476611040081
TI - Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er)
T2 - Journal of Structural Chemistry
AU - Kurazhkovskaya, V S
AU - Dobretsova, E A
AU - Borovikova, E.Yu.
AU - Mal’tsev, V. V.
AU - Leonyuk, N. I.
PY - 2011
DA - 2011/08/01
PB - Pleiades Publishing
SP - 699-707
IS - 4
VL - 52
SN - 0022-4766
SN - 1573-8779
ER -
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@article{2011_Kurazhkovskaya,
author = {V S Kurazhkovskaya and E A Dobretsova and E.Yu. Borovikova and V. V. Mal’tsev and N. I. Leonyuk},
title = {Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er)},
journal = {Journal of Structural Chemistry},
year = {2011},
volume = {52},
publisher = {Pleiades Publishing},
month = {aug},
url = {https://doi.org/10.1134/S0022476611040081},
number = {4},
pages = {699--707},
doi = {10.1134/S0022476611040081}
}
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Kurazhkovskaya, V. S., et al. “Infrared spectroscopy and the structure of rare-earth chromium borates RCr3(BO3)4 (R = La-Er).” Journal of Structural Chemistry, vol. 52, no. 4, Aug. 2011, pp. 699-707. https://doi.org/10.1134/S0022476611040081.
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