Journal of Structural Chemistry, volume 55, issue 6, pages 1091-1096
Crystal structure and spectral luminescent properties of monoiodo-substituted borofluoride complex with dipyrrolylmethene
Publication type: Journal Article
Publication date: 2014-11-01
Journal:
Journal of Structural Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.8
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The crystal structure of the boron(III) complex [BF2L] synthesized for the first time, where L− is the 3,3′,5,5′-tetramethyl-4-ethyl-4′-iododipyrrolylmethene-2,2′ monoanion (iodo-BODIPY, monoclinic crystals: a = 12.0329(6) Å, b = 15.9657(8) Å, c = 8.5080(4) Å, β = 103.753(1)°, V = 1587.64(13) Å3, Z = 4 (Z′ = 1), space group P21/c) is determined. In the structure, two pyrrol rings and the central six-membered ring containing a boron atom are in one plane, perpendicular to which a plane formed by a group of F-B-F atoms is located. The crystal packing is formed by van der Waals interactions. In the electron absorption spectra of iodo-BODIPY solutions in nonpolar solvents, unlike polar ones, a red shift up to 3–8 nm of the maximum of the first intense band is observed, for which the lgɛ value reaches ∼4.71. Along with intense chromophoric properties, the synthesized iodo-BODIPY complex is a sufficiently strong fluorophore and can be used as a fluorescent marker.
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Thermochimica Acta
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Thermochimica Acta
1 publication, 50%
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Journal of Structural Chemistry
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Journal of Structural Chemistry
1 publication, 50%
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Elsevier
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Elsevier
1 publication, 50%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 50%
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Guseva G. B. et al. Crystal structure and spectral luminescent properties of monoiodo-substituted borofluoride complex with dipyrrolylmethene // Journal of Structural Chemistry. 2014. Vol. 55. No. 6. pp. 1091-1096.
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Guseva G. B., Antina E. V., Nuraneeva E. N., Berezin M. B., Vyugin A. I. Crystal structure and spectral luminescent properties of monoiodo-substituted borofluoride complex with dipyrrolylmethene // Journal of Structural Chemistry. 2014. Vol. 55. No. 6. pp. 1091-1096.
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TY - JOUR
DO - 10.1134/S0022476614060122
UR - https://doi.org/10.1134%2FS0022476614060122
TI - Crystal structure and spectral luminescent properties of monoiodo-substituted borofluoride complex with dipyrrolylmethene
T2 - Journal of Structural Chemistry
AU - Berezin, M B
AU - Vyugin, A I
AU - Guseva, G B
AU - Antina, E V
AU - Nuraneeva, E N
PY - 2014
DA - 2014/11/01 00:00:00
PB - Pleiades Publishing
SP - 1091-1096
IS - 6
VL - 55
SN - 0022-4766
SN - 1573-8779
ER -
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@article{2014_Guseva,
author = {M B Berezin and A I Vyugin and G B Guseva and E V Antina and E N Nuraneeva},
title = {Crystal structure and spectral luminescent properties of monoiodo-substituted borofluoride complex with dipyrrolylmethene},
journal = {Journal of Structural Chemistry},
year = {2014},
volume = {55},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134%2FS0022476614060122},
number = {6},
pages = {1091--1096},
doi = {10.1134/S0022476614060122}
}
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MLA
Copy
Guseva, G. B., et al. “Crystal structure and spectral luminescent properties of monoiodo-substituted borofluoride complex with dipyrrolylmethene.” Journal of Structural Chemistry, vol. 55, no. 6, Nov. 2014, pp. 1091-1096. https://doi.org/10.1134%2FS0022476614060122.