Journal of Structural Chemistry, volume 55, issue 8, pages 1484-1495
Features of cation packing in crystal forms of a 18-crown-6-containing styryl dye iodide and feasibility of the solid phase [2+2]-autophotocycloaddition reaction in it
Kuz'mina L. G.
1
,
Vedernikov A.I.
2
,
Howard J. A. K.
3
,
Lermontova E Kh
1
,
Churakov A.V.
1
,
Alfimov M.V.
2
,
Publication type: Journal Article
Publication date: 2014-12-01
Journal:
Journal of Structural Chemistry
Quartile SCImago
Q4
Quartile WOS
Q4
Impact factor: 0.8
ISSN: 00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
X-ray structure determinations of three crystal forms of a 18-crown-6-containing styryl dye of the pyridine series in iodide form (1), containing various solvate molecules, namely water (1a), 2,6-dihydroxyoaphthalene (1b), 1,4-hydroquinone (1c), and analysis of crystal packings of these crystals, together with the previously investigated non-solvated form (crystal 1) and the solvates with benzene and water (crystal 1d) has been carried out. Crystal packing in 1a, 1b, 1c, and 1d involves a stacking leading to dimers of the dye cations, structurally preorganized for the [2+2]-photocycloaddition (PCA) reaction. On irradiation of with visible light, the PCA reaction with the centrosymmetric rctt isomer leads to the cyclobutane derivative formation. In the case of 1a and 1b the PCA proceeds with the retention of crystallinity, while with other solvates crystals are transformed into a glass. The glasses keep the form and the shine of the initial crystals, nevertheless. In the cases of the non-solvated crystal form (1), translation-related stacks form, with the geometry inconsistent with that of the preorganized dimer. These crystals are stable in visible light.
Citations by journals
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1
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Crystallography Reports
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Crystallography Reports
1 publication, 33.33%
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Russian Chemical Bulletin
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Russian Chemical Bulletin
1 publication, 33.33%
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Chemistry - A European Journal
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Chemistry - A European Journal
1 publication, 33.33%
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1
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Citations by publishers
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1
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Pleiades Publishing
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Pleiades Publishing
1 publication, 33.33%
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Springer Nature
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Springer Nature
1 publication, 33.33%
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Wiley
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Wiley
1 publication, 33.33%
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1
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Kuz'mina L. G. et al. Features of cation packing in crystal forms of a 18-crown-6-containing styryl dye iodide and feasibility of the solid phase [2+2]-autophotocycloaddition reaction in it // Journal of Structural Chemistry. 2014. Vol. 55. No. 8. pp. 1484-1495.
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Kuz'mina L. G., Vedernikov A., Howard J. A. K., Lermontova E. Kh., Churakov A., Alfimov M., Gromov S. P. Features of cation packing in crystal forms of a 18-crown-6-containing styryl dye iodide and feasibility of the solid phase [2+2]-autophotocycloaddition reaction in it // Journal of Structural Chemistry. 2014. Vol. 55. No. 8. pp. 1484-1495.
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TY - JOUR
DO - 10.1134/S0022476614080162
UR - https://doi.org/10.1134%2FS0022476614080162
TI - Features of cation packing in crystal forms of a 18-crown-6-containing styryl dye iodide and feasibility of the solid phase [2+2]-autophotocycloaddition reaction in it
T2 - Journal of Structural Chemistry
AU - Kuz'mina, L. G.
AU - Vedernikov, A.I.
AU - Howard, J. A. K.
AU - Lermontova, E Kh
AU - Churakov, A.V.
AU - Alfimov, M.V.
AU - Gromov, S P
PY - 2014
DA - 2014/12/01 00:00:00
PB - Pleiades Publishing
SP - 1484-1495
IS - 8
VL - 55
SN - 0022-4766
SN - 1573-8779
ER -
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@article{2014_Kuz'mina,
author = {L. G. Kuz'mina and A.I. Vedernikov and J. A. K. Howard and E Kh Lermontova and A.V. Churakov and M.V. Alfimov and S P Gromov},
title = {Features of cation packing in crystal forms of a 18-crown-6-containing styryl dye iodide and feasibility of the solid phase [2+2]-autophotocycloaddition reaction in it},
journal = {Journal of Structural Chemistry},
year = {2014},
volume = {55},
publisher = {Pleiades Publishing},
month = {dec},
url = {https://doi.org/10.1134%2FS0022476614080162},
number = {8},
pages = {1484--1495},
doi = {10.1134/S0022476614080162}
}
Cite this
MLA
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Kuz'mina, L. G., et al. “Features of cation packing in crystal forms of a 18-crown-6-containing styryl dye iodide and feasibility of the solid phase [2+2]-autophotocycloaddition reaction in it.” Journal of Structural Chemistry, vol. 55, no. 8, Dec. 2014, pp. 1484-1495. https://doi.org/10.1134%2FS0022476614080162.