volume 62 issue 3 pages 436-442

BENZENOID-QUINOID TAUTOMERISM OF SALICYLIDENIMINES: CRYSTAL STRUCTURES OF 5-BROMO- (HL1) AND 3-NITRO-SALICYLIDENE- (2-MORPHOLINO)ETHYLIMINE (HL2)

Publication typeJournal Article
Publication date2021-03-01
scimago Q4
wos Q4
SJR0.211
CiteScore1.9
Impact factor1.4
ISSN00224766, 15738779
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Two azomethynes, namely, derivatives of 5-bromo- and 3-nitrosalicyl aldehydes and 2-morpholinoethylamine (HL1, Z = Br and HL2, Z = NO2; in HL1,2 R = CH2CH2N(CH2)4O) are synthesized and analyzed by IR spectroscopy and single crystal X-ray diffraction. A benzenoid (enolimine) tautomeric form (a hydrogen atom is located at an oxygen atom) occurs in HL1. The structure is stabilized by an intramolecular О1–Н1В…N1 hydrogen bond (О–H 0.87(4) Å, H…N 1.83(4) Å, O…N 2.586(4) Å, ОHN angle 143(4)°). The HL2 molecule crystallizes in the quinoidal (quinone amine) tautomeric form with the intramolecular N1–Н1…O2 hydrogen bond (N–H 0.87(2) Å, H…O 1.99(2) Å, O…N 2.659(2) Å, NHO angle 134(2)°).
Found 
Found 

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Sergienko V. S. et al. BENZENOID-QUINOID TAUTOMERISM OF SALICYLIDENIMINES: CRYSTAL STRUCTURES OF 5-BROMO- (HL1) AND 3-NITRO-SALICYLIDENE- (2-MORPHOLINO)ETHYLIMINE (HL2) // Journal of Structural Chemistry. 2021. Vol. 62. No. 3. pp. 436-442.
GOST all authors (up to 50) Copy
Sergienko V. S., Abramenko V. L., Churakov A., Surazhskaya M. D. BENZENOID-QUINOID TAUTOMERISM OF SALICYLIDENIMINES: CRYSTAL STRUCTURES OF 5-BROMO- (HL1) AND 3-NITRO-SALICYLIDENE- (2-MORPHOLINO)ETHYLIMINE (HL2) // Journal of Structural Chemistry. 2021. Vol. 62. No. 3. pp. 436-442.
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TY - JOUR
DO - 10.1134/S0022476621030100
UR - https://link.springer.com/10.1134/S0022476621030100
TI - BENZENOID-QUINOID TAUTOMERISM OF SALICYLIDENIMINES: CRYSTAL STRUCTURES OF 5-BROMO- (HL1) AND 3-NITRO-SALICYLIDENE- (2-MORPHOLINO)ETHYLIMINE (HL2)
T2 - Journal of Structural Chemistry
AU - Sergienko, V S
AU - Abramenko, V L
AU - Churakov, A.V.
AU - Surazhskaya, M D
PY - 2021
DA - 2021/03/01
PB - Pleiades Publishing
SP - 436-442
IS - 3
VL - 62
SN - 0022-4766
SN - 1573-8779
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2021_Sergienko,
author = {V S Sergienko and V L Abramenko and A.V. Churakov and M D Surazhskaya},
title = {BENZENOID-QUINOID TAUTOMERISM OF SALICYLIDENIMINES: CRYSTAL STRUCTURES OF 5-BROMO- (HL1) AND 3-NITRO-SALICYLIDENE- (2-MORPHOLINO)ETHYLIMINE (HL2)},
journal = {Journal of Structural Chemistry},
year = {2021},
volume = {62},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://link.springer.com/10.1134/S0022476621030100},
number = {3},
pages = {436--442},
doi = {10.1134/S0022476621030100}
}
MLA
Cite this
MLA Copy
Sergienko, V. S., et al. “BENZENOID-QUINOID TAUTOMERISM OF SALICYLIDENIMINES: CRYSTAL STRUCTURES OF 5-BROMO- (HL1) AND 3-NITRO-SALICYLIDENE- (2-MORPHOLINO)ETHYLIMINE (HL2).” Journal of Structural Chemistry, vol. 62, no. 3, Mar. 2021, pp. 436-442. https://link.springer.com/10.1134/S0022476621030100.