Covalent Functionalization of Few-Layer Black Phosphorus by the Complex [NiBr2 (phen)] (phen = 1,10-Phenanthroline)
Aidar M Kuchkaev
1
,
Airat M. Kuchkaev
1
,
A. V. Sukhov
1, 2
,
S V Saparina
3
,
O I Gnezdilov
3
,
A. E. Klimovitskii
2
,
S A Ziganshina
4
,
I R Nizameev
1
,
B. A. Faizullin
1
,
O G Sinyashin
1
,
D G Yakhvarov
1
Publication type: Journal Article
Publication date: 2024-04-01
scimago Q4
wos Q4
SJR: 0.211
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00224766, 15738779
Abstract
A 2D material few-layer black phosphorus (FLBP) has promising applications in various fields of chemistry and physics due to its unique electronic and optical properties. Chemical functionalization of the FLBP surface is an effective strategy for improving the oxidative stability of the material, tuning its intrinsic properties or endowing it with new properties. The present work proposes an approach to the immobilization of the [NiBr2(phen)] complex (phen = 1, 10-phenanthroline) on the FLBP surface via covalent functionalization of FLBP with 1,10-phenanthroline and subsequent complexation with NiBr2. The obtained FLBP-based materials functionalized by the [NiBr2(phen)] complex were characterized by a set of physicochemical methods such as transmission electron microscopy, atomic force microscopy, solid-state NMR, energy-dispersive spectroscopy, Raman spectroscopy, and IR spectroscopy.
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Kuchkaev A. M. et al. Covalent Functionalization of Few-Layer Black Phosphorus by the Complex [NiBr2(phen)] (phen = 1,10-Phenanthroline) // Journal of Structural Chemistry. 2024. Vol. 65. No. 4. pp. 643-654.
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Kuchkaev A. M., Kuchkaev A. M., Sukhov A. V., Saparina S. V., Gnezdilov O. I., Klimovitskii A. E., Ziganshina S. A., Nizameev I. R., Faizullin B. A., Sinyashin O. G., Yakhvarov D. G. Covalent Functionalization of Few-Layer Black Phosphorus by the Complex [NiBr2(phen)] (phen = 1,10-Phenanthroline) // Journal of Structural Chemistry. 2024. Vol. 65. No. 4. pp. 643-654.
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TY - JOUR
DO - 10.1134/S0022476624040012
UR - https://link.springer.com/10.1134/S0022476624040012
TI - Covalent Functionalization of Few-Layer Black Phosphorus by the Complex [NiBr2(phen)] (phen = 1,10-Phenanthroline)
T2 - Journal of Structural Chemistry
AU - Kuchkaev, Aidar M
AU - Kuchkaev, Airat M.
AU - Sukhov, A. V.
AU - Saparina, S V
AU - Gnezdilov, O I
AU - Klimovitskii, A. E.
AU - Ziganshina, S A
AU - Nizameev, I R
AU - Faizullin, B. A.
AU - Sinyashin, O G
AU - Yakhvarov, D G
PY - 2024
DA - 2024/04/01
PB - Pleiades Publishing
SP - 643-654
IS - 4
VL - 65
SN - 0022-4766
SN - 1573-8779
ER -
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BibTex (up to 50 authors)
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@article{2024_Kuchkaev,
author = {Aidar M Kuchkaev and Airat M. Kuchkaev and A. V. Sukhov and S V Saparina and O I Gnezdilov and A. E. Klimovitskii and S A Ziganshina and I R Nizameev and B. A. Faizullin and O G Sinyashin and D G Yakhvarov},
title = {Covalent Functionalization of Few-Layer Black Phosphorus by the Complex [NiBr2(phen)] (phen = 1,10-Phenanthroline)},
journal = {Journal of Structural Chemistry},
year = {2024},
volume = {65},
publisher = {Pleiades Publishing},
month = {apr},
url = {https://link.springer.com/10.1134/S0022476624040012},
number = {4},
pages = {643--654},
doi = {10.1134/S0022476624040012}
}
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MLA
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Kuchkaev, Aidar M., et al. “Covalent Functionalization of Few-Layer Black Phosphorus by the Complex [NiBr2(phen)] (phen = 1,10-Phenanthroline).” Journal of Structural Chemistry, vol. 65, no. 4, Apr. 2024, pp. 643-654. https://link.springer.com/10.1134/S0022476624040012.