Ion pairs formed in metallocene-based systems by the "double activation" mechanism and their catalytic activity
Publication type: Journal Article
Publication date: 2006-03-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modelling and Simulation
Abstract
The DFT method is used to study the interaction between metallocene catalyst precursors used in ethylene and propylene polymerization and two molecules of the Al-containing cocatalyst Al(C6F5)3. The participation of two Al centers in metallocene activation accounts for the catalytic activity and other properties of the catalytic systems. Two energy parameters characterizing the number of active sites and the polymerization rate per site are calculated.
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Total citations:
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Citations from 2024:
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GOST
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Ustynyuk L. et al. Ion pairs formed in metallocene-based systems by the "double activation" mechanism and their catalytic activity // Kinetics and Catalysis. 2006. Vol. 47. No. 2. pp. 213-220.
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Ustynyuk L., Fushman E. A., Razavi A. Ion pairs formed in metallocene-based systems by the "double activation" mechanism and their catalytic activity // Kinetics and Catalysis. 2006. Vol. 47. No. 2. pp. 213-220.
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RIS
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TY - JOUR
DO - 10.1134/S0023158406020091
UR - http://link.springer.com/10.1134/S0023158406020091
TI - Ion pairs formed in metallocene-based systems by the "double activation" mechanism and their catalytic activity
T2 - Kinetics and Catalysis
AU - Ustynyuk, L.Yu.
AU - Fushman, E A
AU - Razavi, A.
PY - 2006
DA - 2006/03/01
PB - Pleiades Publishing
SP - 213-220
IS - 2
VL - 47
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Ustynyuk,
author = {L.Yu. Ustynyuk and E A Fushman and A. Razavi},
title = {Ion pairs formed in metallocene-based systems by the "double activation" mechanism and their catalytic activity},
journal = {Kinetics and Catalysis},
year = {2006},
volume = {47},
publisher = {Pleiades Publishing},
month = {mar},
url = {http://link.springer.com/10.1134/S0023158406020091},
number = {2},
pages = {213--220},
doi = {10.1134/S0023158406020091}
}
Cite this
MLA
Copy
Ustynyuk, L.Yu., et al. “Ion pairs formed in metallocene-based systems by the "double activation" mechanism and their catalytic activity.” Kinetics and Catalysis, vol. 47, no. 2, Mar. 2006, pp. 213-220. http://link.springer.com/10.1134/S0023158406020091.
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