Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals
Publication type: Journal Article
Publication date: 2009-05-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modelling and Simulation
Abstract
The kinetics of reactions of palladium(II) acetate with cobalt(II), nickel(II), and copper(II) acetates were studied by spectrophotometry. These reactions produce heterobimetallic complexes PdII(μ-OOCMe)4MII(OH2)(HOOCMe)2, where M = Co, Ni, or Cu. These reactions are very slow in carefully dehydrated (<0.01% H2O) acetic acid, but are considerably enhanced by water or acetonitrile. Our data indicate that the activation of the kinetically inert ring structure of the initial palladium complex Pd3(μ-OOCMe)6 by means of the nucleophilic attack of an H2O or acetonitrile molecule is the key step of the reaction mechanism.
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GOST
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Akhmadullina N. S. et al. Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals // Kinetics and Catalysis. 2009. Vol. 50. No. 3. pp. 396-400.
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Akhmadullina N. S., Cherkashina N. V., Kozitsyna N., Gekhman A. E., Vargaftik M. Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals // Kinetics and Catalysis. 2009. Vol. 50. No. 3. pp. 396-400.
Cite this
RIS
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TY - JOUR
DO - 10.1134/S0023158409030094
UR - http://link.springer.com/10.1134/S0023158409030094
TI - Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals
T2 - Kinetics and Catalysis
AU - Akhmadullina, N S
AU - Cherkashina, N V
AU - Kozitsyna, N.Yu.
AU - Gekhman, A E
AU - Vargaftik, M.N.
PY - 2009
DA - 2009/05/01
PB - Pleiades Publishing
SP - 396-400
IS - 3
VL - 50
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Akhmadullina,
author = {N S Akhmadullina and N V Cherkashina and N.Yu. Kozitsyna and A E Gekhman and M.N. Vargaftik},
title = {Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals},
journal = {Kinetics and Catalysis},
year = {2009},
volume = {50},
publisher = {Pleiades Publishing},
month = {may},
url = {http://link.springer.com/10.1134/S0023158409030094},
number = {3},
pages = {396--400},
doi = {10.1134/S0023158409030094}
}
Cite this
MLA
Copy
Akhmadullina, N. S., et al. “Unexpected participation of nucleophiles in the reaction of palladium(II) acetate with divalent 3d metals.” Kinetics and Catalysis, vol. 50, no. 3, May. 2009, pp. 396-400. http://link.springer.com/10.1134/S0023158409030094.