Kinetics and Catalysis, volume 50, issue 5, pages 627-635

Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole

A.A. Paletsky ¹

N V Budachev ¹

O P Korobeinichev ¹

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Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia |

Publication type: Journal Article

Publication date: 2009-09-01

Pleiades Publishing

Journal: Kinetics and Catalysis

Quartile SCImago

Quartile WOS

Impact factor: 1.1

ISSN: 00231584, 16083210

DOI: 10.1134/s0023158409050036

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General Chemistry

Catalysis

Computer Science Applications

Modeling and Simulation

Abstract

The kinetics of 5-aminotetrazole thermal decomposition in the condensed phase at high heating rates (∼100 K/s) was studied by the dynamic mass spectrometric thermal analysis using a molecular beam sampling system, and the product composition was determined. Two routes of 5-aminotetrazole decomposition were distinguished, one yielding HN3 and NH2CN (route 1), and the other N2 and CH3N3 (route 2). The activation energy and rate constant of 5-AT decomposition were determined for each route.

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Paletsky A., Budachev N. V., Korobeinichev O. P. Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole // Kinetics and Catalysis. 2009. Vol. 50. No. 5. pp. 627-635.

GOST all authors (up to 50) Copy

Paletsky A., Budachev N. V., Korobeinichev O. P. Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole // Kinetics and Catalysis. 2009. Vol. 50. No. 5. pp. 627-635.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1134/s0023158409050036

UR - https://doi.org/10.1134/s0023158409050036

TI - Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole

T2 - Kinetics and Catalysis

AU - Paletsky, A.A.

AU - Budachev, N V

AU - Korobeinichev, O P

PY - 2009

DA - 2009/09/01 00:00:00

PB - Pleiades Publishing

SP - 627-635

IS - 5

VL - 50

SN - 0023-1584

SN - 1608-3210

ER -

BibTex |

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BibTex Copy

@article{2009_Paletsky,

author = {A.A. Paletsky and N V Budachev and O P Korobeinichev},

title = {Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole},

journal = {Kinetics and Catalysis},

year = {2009},

volume = {50},

publisher = {Pleiades Publishing},

month = {sep},

url = {https://doi.org/10.1134/s0023158409050036},

number = {5},

pages = {627--635},

doi = {10.1134/s0023158409050036}

}

MLA

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MLA Copy

Paletsky, A.A., et al. “Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole.” Kinetics and Catalysis, vol. 50, no. 5, Sep. 2009, pp. 627-635. https://doi.org/10.1134/s0023158409050036.

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Pleiades Publishing

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Kinetics and Catalysis

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00231584 (Print)
16083210 (Electronic)