Kinetics and Catalysis, volume 50, issue 5, pages 627-635
Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole
Publication type: Journal Article
Publication date: 2009-09-01
Journal:
Kinetics and Catalysis
Quartile SCImago
Q3
Quartile WOS
Q4
SJR: 0.254
CiteScore: 2.1
Impact factor: 1.3
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The kinetics of 5-aminotetrazole thermal decomposition in the condensed phase at high heating rates (∼100 K/s) was studied by the dynamic mass spectrometric thermal analysis using a molecular beam sampling system, and the product composition was determined. Two routes of 5-aminotetrazole decomposition were distinguished, one yielding HN3 and NH2CN (route 1), and the other N2 and CH3N3 (route 2). The activation energy and rate constant of 5-AT decomposition were determined for each route.
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Paletsky A., Budachev N. V., Korobeinichev O. P. Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole // Kinetics and Catalysis. 2009. Vol. 50. No. 5. pp. 627-635.
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Paletsky A., Budachev N. V., Korobeinichev O. P. Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole // Kinetics and Catalysis. 2009. Vol. 50. No. 5. pp. 627-635.
Cite this
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TY - JOUR
DO - 10.1134/s0023158409050036
UR - https://doi.org/10.1134/s0023158409050036
TI - Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole
T2 - Kinetics and Catalysis
AU - Paletsky, A.A.
AU - Budachev, N V
AU - Korobeinichev, O P
PY - 2009
DA - 2009/09/01
PB - Pleiades Publishing
SP - 627-635
IS - 5
VL - 50
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex
Copy
@article{2009_Paletsky,
author = {A.A. Paletsky and N V Budachev and O P Korobeinichev},
title = {Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole},
journal = {Kinetics and Catalysis},
year = {2009},
volume = {50},
publisher = {Pleiades Publishing},
month = {sep},
url = {https://doi.org/10.1134/s0023158409050036},
number = {5},
pages = {627--635},
doi = {10.1134/s0023158409050036}
}
Cite this
MLA
Copy
Paletsky, A.A., et al. “Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole.” Kinetics and Catalysis, vol. 50, no. 5, Sep. 2009, pp. 627-635. https://doi.org/10.1134/s0023158409050036.