Synthesis and physicochemical characterization of palladium-cerium oxide catalysts for the low-temperature oxidation of carbon monoxide
E M Slavinskaya
1
,
A.I. BORONIN
1
,
I. G. Danilova
1
,
Yu I Amosov
1
,
A.S Ivanova
1
,
P. A. Kuznetsov
1
,
I.A Polukhina
1
,
R V Gulyaev
1
,
A I Stadnichenko
1
,
S.V Koshcheev
1
,
V.I. Zaikovskii
1
,
A.S Noskov
1
Publication type: Journal Article
Publication date: 2009-11-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The effect of CeO2 preparation procedure on the electronic and structural states of the active component of Pd/CeO2 catalysts and their activity in the low-temperature reaction of CO oxidation was studied. The following two nonequivalent states of palladium were detected in the catalysts having low-temperature activity using XPS and IR spectroscopy: Pd0(Pdδ+) as the constituent of a palladium-reduced interaction phase and Pd2+ as the constituent of a palladium-oxidized interaction phase Pd x CeO2 −δ. It was found that the procedure used for preparing a CeO2 support considerably affected the formation of these phases and quantitative ratios between them. It was demonstrated that the palladium-oxidized interaction phase was responsible for low-temperature activity, whereas the palladium-reduced interaction phase was responsible for activity in the region of medium and high temperatures.
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12
Total citations:
12
Citations from 2025:
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(8.33%)
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Slavinskaya E. M. et al. Synthesis and physicochemical characterization of palladium-cerium oxide catalysts for the low-temperature oxidation of carbon monoxide // Kinetics and Catalysis. 2009. Vol. 50. No. 6. pp. 819-823.
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Slavinskaya E. M., BORONIN A., Danilova I. G., Amosov Yu. I., Ivanova A., Kuznetsov P. A., Polukhina I., Gulyaev R. V., Stadnichenko A. I., Koshcheev S., Zaikovskii V., Noskov A. Synthesis and physicochemical characterization of palladium-cerium oxide catalysts for the low-temperature oxidation of carbon monoxide // Kinetics and Catalysis. 2009. Vol. 50. No. 6. pp. 819-823.
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RIS
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TY - JOUR
DO - 10.1134/S0023158409060044
UR - https://doi.org/10.1134/S0023158409060044
TI - Synthesis and physicochemical characterization of palladium-cerium oxide catalysts for the low-temperature oxidation of carbon monoxide
T2 - Kinetics and Catalysis
AU - Slavinskaya, E M
AU - BORONIN, A.I.
AU - Danilova, I. G.
AU - Amosov, Yu I
AU - Ivanova, A.S
AU - Kuznetsov, P. A.
AU - Polukhina, I.A
AU - Gulyaev, R V
AU - Stadnichenko, A I
AU - Koshcheev, S.V
AU - Zaikovskii, V.I.
AU - Noskov, A.S
PY - 2009
DA - 2009/11/01
PB - Pleiades Publishing
SP - 819-823
IS - 6
VL - 50
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Slavinskaya,
author = {E M Slavinskaya and A.I. BORONIN and I. G. Danilova and Yu I Amosov and A.S Ivanova and P. A. Kuznetsov and I.A Polukhina and R V Gulyaev and A I Stadnichenko and S.V Koshcheev and V.I. Zaikovskii and A.S Noskov},
title = {Synthesis and physicochemical characterization of palladium-cerium oxide catalysts for the low-temperature oxidation of carbon monoxide},
journal = {Kinetics and Catalysis},
year = {2009},
volume = {50},
publisher = {Pleiades Publishing},
month = {nov},
url = {https://doi.org/10.1134/S0023158409060044},
number = {6},
pages = {819--823},
doi = {10.1134/S0023158409060044}
}
Cite this
MLA
Copy
Slavinskaya, E. M., et al. “Synthesis and physicochemical characterization of palladium-cerium oxide catalysts for the low-temperature oxidation of carbon monoxide.” Kinetics and Catalysis, vol. 50, no. 6, Nov. 2009, pp. 819-823. https://doi.org/10.1134/S0023158409060044.
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