Effect of preparation procedure on the properties of CeO2
Тип публикации: Journal Article
Дата публикации: 2010-02-01
scimago Q3
wos Q4
БС2
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Краткое описание
The effect of preparation procedure on the physicochemical and catalytic properties of CeO2 was studied. Differences in the electronic and structural characteristics of CeO2 depending on preparation procedure and treatment temperature were found using X-ray diffraction analysis, transmission electron microscopy, UV-visible electronic spectroscopy, and X-ray photoelectron spectroscopy. With the use of the temperature-programmed reaction with CO, it was demonstrated that CeO2 samples with a high concentration of point defects—oxygen vacancies caused by the presence of Ce3+—were characterized by an increased mobility of bulk oxygen. The samples of CeO2 with a high concentration of structural defects—micropores of size 1–2 nm and stepwise vicinal faces in crystallites—exhibited a high catalytic activity in the reaction of CO oxidation.
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Danilova I. G. et al. Effect of preparation procedure on the properties of CeO2 // Kinetics and Catalysis. 2010. Vol. 51. No. 1. pp. 143-148.
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Danilova I. G., Slavinskaya E. M., Zaikovskii V., Ivanova A., BORONIN A., Gulyaev R. V., Amosov Yu. I. Effect of preparation procedure on the properties of CeO2 // Kinetics and Catalysis. 2010. Vol. 51. No. 1. pp. 143-148.
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TY - JOUR
DO - 10.1134/S0023158410010246
UR - https://doi.org/10.1134/S0023158410010246
TI - Effect of preparation procedure on the properties of CeO2
T2 - Kinetics and Catalysis
AU - Danilova, I. G.
AU - Slavinskaya, E M
AU - Zaikovskii, V.I.
AU - Ivanova, A.S
AU - BORONIN, A.I.
AU - Gulyaev, R V
AU - Amosov, Yu I
PY - 2010
DA - 2010/02/01
PB - Pleiades Publishing
SP - 143-148
IS - 1
VL - 51
SN - 0023-1584
SN - 1608-3210
ER -
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@article{2010_Danilova,
author = {I. G. Danilova and E M Slavinskaya and V.I. Zaikovskii and A.S Ivanova and A.I. BORONIN and R V Gulyaev and Yu I Amosov},
title = {Effect of preparation procedure on the properties of CeO2},
journal = {Kinetics and Catalysis},
year = {2010},
volume = {51},
publisher = {Pleiades Publishing},
month = {feb},
url = {https://doi.org/10.1134/S0023158410010246},
number = {1},
pages = {143--148},
doi = {10.1134/S0023158410010246}
}
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Danilova, I. G., et al. “Effect of preparation procedure on the properties of CeO2.” Kinetics and Catalysis, vol. 51, no. 1, Feb. 2010, pp. 143-148. https://doi.org/10.1134/S0023158410010246.