Cocatalytic effect of palladium and zinc in the condensation of alcohol carbon backbones into hydrocarbons
Publication type: Journal Article
Publication date: 2011-03-01
scimago Q3
wos Q4
SJR: 0.260
CiteScore: 1.9
Impact factor: 1.4
ISSN: 00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
The results of the direct conversion of ethanol and its mixture with glycerol into a C4–C10+ alkane and olefin fraction in the presence of Pd-, Zn-, and Pd-Zn-containing catalysts, which were prepared by supporting homo- and heterometallic acetate complexes onto the surface of γ-Al2O3, are reported. It was found that, in the presence of mono- and bicomponent Pd-ZnO (Pd; ZnO)/γ-Al2O3 systems, selectivity in the formation of alkanes, olefins, or their mixtures in the target fraction can be controlled as a result of the cocatalytic effect of active components that are responsible for the catalyst activity in condensation and hydrogenation reactions. The structures of the active components were studied and the genesis of the catalytic systems was characterized using XAFS, XPS, and XRD analysis. It was found that the addition of glycerol considerably increased the yield of the target hydrocarbon fraction.
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GOST
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Chistyakov A. V. et al. Cocatalytic effect of palladium and zinc in the condensation of alcohol carbon backbones into hydrocarbons // Kinetics and Catalysis. 2011. Vol. 52. No. 2. pp. 258-272.
GOST all authors (up to 50)
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Chistyakov A. V., Tsodikov M. V., Murzin V. Yu., Yandieva F. A., Zubavichus Y. V., Kozitsyna N., Gekhman A. E., Kriventsov V., Moiseev I. I. Cocatalytic effect of palladium and zinc in the condensation of alcohol carbon backbones into hydrocarbons // Kinetics and Catalysis. 2011. Vol. 52. No. 2. pp. 258-272.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1134/S0023158411020030
UR - https://doi.org/10.1134/S0023158411020030
TI - Cocatalytic effect of palladium and zinc in the condensation of alcohol carbon backbones into hydrocarbons
T2 - Kinetics and Catalysis
AU - Chistyakov, A. V.
AU - Tsodikov, M V
AU - Murzin, V Yu
AU - Yandieva, F A
AU - Zubavichus, Ya. V.
AU - Kozitsyna, N.Yu.
AU - Gekhman, A E
AU - Kriventsov, V.V.
AU - Moiseev, I. I.
PY - 2011
DA - 2011/03/01
PB - Pleiades Publishing
SP - 258-272
IS - 2
VL - 52
SN - 0023-1584
SN - 1608-3210
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2011_Chistyakov,
author = {A. V. Chistyakov and M V Tsodikov and V Yu Murzin and F A Yandieva and Ya. V. Zubavichus and N.Yu. Kozitsyna and A E Gekhman and V.V. Kriventsov and I. I. Moiseev},
title = {Cocatalytic effect of palladium and zinc in the condensation of alcohol carbon backbones into hydrocarbons},
journal = {Kinetics and Catalysis},
year = {2011},
volume = {52},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S0023158411020030},
number = {2},
pages = {258--272},
doi = {10.1134/S0023158411020030}
}
Cite this
MLA
Copy
Chistyakov, A. V., et al. “Cocatalytic effect of palladium and zinc in the condensation of alcohol carbon backbones into hydrocarbons.” Kinetics and Catalysis, vol. 52, no. 2, Mar. 2011, pp. 258-272. https://doi.org/10.1134/S0023158411020030.
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