volume 52 issue 2 pages 282-295

Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts

E M Slavinskaya 1
R V Gulyaev 1
O A Stonkus 1, 2
A V Zadesenets 2, 3
P E Plyusnin 2, 3
Yu. V. Shubin 2, 3
S V Korenev 2, 3
A.S Ivanova 1
V.I. Zaikovskii 1
I. G. Danilova 1
Publication typeJournal Article
Publication date2011-03-01
scimago Q3
wos Q4
SJR0.260
CiteScore1.9
Impact factor1.4
ISSN00231584, 16083210
General Chemistry
Catalysis
Computer Science Applications
Modeling and Simulation
Abstract
Catalysts containing cerium oxide as a support and platinum and palladium as active components for the low-temperature oxidation of carbon monoxide were studied. The catalysts were synthesized in accordance with original procedures with the use of palladium and platinum complex salts. Regardless of preparation procedure, the samples prepared with the use of only platinum precursors did not exhibit activity at a low temperature because only metal and oxide (PtO, PtO2) nanoparticles were formed on the surface of CeO2. Unlike platinum, palladium can be dispersed on the surface of CeO2 to a maximum extent up to an almost an ionic (atomic) state, and it forms mixed surface phases with cerium oxide. In a mixed palladium-platinum catalyst, the ability of platinum to undergo dispersion under the action of palladium also increased; as a result, a combined surface phase with the formula Pd x Pt y CeO2 − δ, which exhibits catalytic activity at low temperatures, was formed.
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Slavinskaya E. M. et al. Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts // Kinetics and Catalysis. 2011. Vol. 52. No. 2. pp. 282-295.
GOST all authors (up to 50) Copy
Slavinskaya E. M., Gulyaev R. V., Stonkus O. A., Zadesenets A. V., Plyusnin P. E., Shubin Y. V., Korenev S. V., Ivanova A., Zaikovskii V., Danilova I. G., BORONIN A. Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts // Kinetics and Catalysis. 2011. Vol. 52. No. 2. pp. 282-295.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1134/S0023158411020182
UR - https://doi.org/10.1134/S0023158411020182
TI - Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts
T2 - Kinetics and Catalysis
AU - Slavinskaya, E M
AU - Gulyaev, R V
AU - Stonkus, O A
AU - Zadesenets, A V
AU - Plyusnin, P E
AU - Shubin, Yu. V.
AU - Korenev, S V
AU - Ivanova, A.S
AU - Zaikovskii, V.I.
AU - Danilova, I. G.
AU - BORONIN, A.I.
PY - 2011
DA - 2011/03/01
PB - Pleiades Publishing
SP - 282-295
IS - 2
VL - 52
SN - 0023-1584
SN - 1608-3210
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2011_Slavinskaya,
author = {E M Slavinskaya and R V Gulyaev and O A Stonkus and A V Zadesenets and P E Plyusnin and Yu. V. Shubin and S V Korenev and A.S Ivanova and V.I. Zaikovskii and I. G. Danilova and A.I. BORONIN},
title = {Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts},
journal = {Kinetics and Catalysis},
year = {2011},
volume = {52},
publisher = {Pleiades Publishing},
month = {mar},
url = {https://doi.org/10.1134/S0023158411020182},
number = {2},
pages = {282--295},
doi = {10.1134/S0023158411020182}
}
MLA
Cite this
MLA Copy
Slavinskaya, E. M., et al. “Low-temperature oxidation of carbon monoxide on Pd(Pt)/CeO2 catalysts prepared from complex salts.” Kinetics and Catalysis, vol. 52, no. 2, Mar. 2011, pp. 282-295. https://doi.org/10.1134/S0023158411020182.
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